a-chloro-dc-[2-(2'-pyridyl)phenyl-N',C]-b-(triphenylphosphine)platinum

Base Information

• Chemical Name: a-chloro-dc-[2-(2'-pyridyl)phenyl-N',C]-b-(triphenylphosphine)platinum
• CAS No.: 872729-59-4
• Molecular Formula: C₂₉H₂₃ClNPPt
• Molecular Weight: 647.015
• Mol file: 872729-59-4.mol

Synonyms:a-chloro-dc-[2-(2'-pyridyl)phenyl-N',C]-b-(triphenylphosphine)platinum

Chemical Property of a-chloro-dc-[2-(2'-pyridyl)phenyl-N',C]-b-(triphenylphosphine)platinum

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of a-chloro-dc-[2-(2'-pyridyl)phenyl-N',C]-b-(triphenylphosphine)platinum

There total 5 articles about a-chloro-dc-[2-(2'-pyridyl)phenyl-N',C]-b-(triphenylphosphine)platinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

Pt(2-phenylpyridine (C(2')(-H)))Cl(dimethylsulfoxide) + triphenylphosphine (603-35-0) → a-chloro-dc-[2-(2'-pyridyl)phenyl-N',C]-b-(triphenylphosphine)platinum (872729-59-4)

Guidance literature:

In acetone; at 20 ℃; for 1h;

DOI:10.1007/s13738-013-0389-z

Reference yield: 85.0%

[Pt(κ2-C,N-2-phenylpyridine)(dimethyl sulfoxide)Cl] + triphenylphosphine (603-35-0) → a-chloro-dc-[2-(2'-pyridyl)phenyl-N',C]-b-(triphenylphosphine)platinum (872729-59-4)

Guidance literature:

In hexane; dichloromethane;

DOI:10.1021/acs.bioconjchem.6b00598

Reference yield: 50.0%

di-μ-chlorobis[2-(2-pyridinyl-κN)-phenyl-κC]di-platinum + triphenylphosphine (603-35-0) → a-chloro-dc-[2-(2'-pyridyl)phenyl-N',C]-b-(triphenylphosphine)platinum (872729-59-4)

Guidance literature:

In dichloromethane; PPh3 added to stirred suspn. of Pt complex in CH2Cl2; stirred at room temp. until complete dissolution; pentane added; filtered; ppt. washed with pentane; dissolved in CH2Cl2 at room temp.; soln. filtered; pptd. by slow addition of pentane; dried at room temp.; elem. anal.;

DOI:10.1139/v05-109

upstream raw materials:

triphenylphosphine

2-phenylpyridine

a-chloro-b-(dimethylsulfoxide-S'')-dc-[2-(2'-pyridyl)phenyl-N',C]platinum