N-[[[(2-propenyloxy)carbonyl]-N'-(benzyl)amino]sulfonyl]-N-(2-propenyl)-(S)-valine methyl ester

Base Information

Chemical Name:N-[[[(2-propenyloxy)carbonyl]-N'-(benzyl)amino]sulfonyl]-N-(2-propenyl)-(S)-valine methyl ester
CAS No.:861632-11-3
Molecular Formula:C₂₀H₂₈N₂O₆S
Molecular Weight:424.518
Hs Code.:

Synonyms:N-[[[(2-propenyloxy)carbonyl]-N'-(benzyl)amino]sulfonyl]-N-(2-propenyl)-(S)-valine methyl ester

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Chemical Property of N-[[[(2-propenyloxy)carbonyl]-N'-(benzyl)amino]sulfonyl]-N-(2-propenyl)-(S)-valine methyl ester

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Technology Process of N-[[[(2-propenyloxy)carbonyl]-N'-(benzyl)amino]sulfonyl]-N-(2-propenyl)-(S)-valine methyl ester

There total 2 articles about N-[[[(2-propenyloxy)carbonyl]-N'-(benzyl)amino]sulfonyl]-N-(2-propenyl)-(S)-valine methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 861632-10-2
N-[[[(2-propenyloxy)carbonyl]amino]sulfonyl]-N-(2-propenyl)-(S)-valine methyl ester

: 100-51-6,185532-71-2
benzyl alcohol

: 861632-11-3
N-[[[(2-propenyloxy)carbonyl]-N'-(benzyl)amino]sulfonyl]-N-(2-propenyl)-(S)-valine methyl ester

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; for 6h;
DOI:10.1016/j.tet.2005.03.140

Reference yield:

: 73270-64-1
N-Allylated valine methyl ester

: 861632-11-3
N-[[[(2-propenyloxy)carbonyl]-N'-(benzyl)amino]sulfonyl]-N-(2-propenyl)-(S)-valine methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: CH₂Cl₂ / 0.17 h / 0 °C

1.2: 79 percent / triethylamine / CH₂Cl₂ / 12 h / 0 °C

2.1: 92 percent / DEAD; PPh₃ / tetrahydrofuran / 6 h

With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; dichloromethane; 2.1: Mitsunobu benzylation;
DOI:10.1016/j.tet.2005.03.140

Reference yield: 69.0%

: 861632-11-3
N-[[[(2-propenyloxy)carbonyl]-N'-(benzyl)amino]sulfonyl]-N-(2-propenyl)-(S)-valine methyl ester

: (2S)-2-(3-benzyl-2,4,4-trioxo-3,4,6,9-tetrahydro-2H-4λ⁶-[1,4,3,5]oxathiadiazonin-5-yl)-3-methyl-butyric acid methyl ester

Guidance literature:: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; for 18h; Heating;
DOI:10.1016/j.tet.2005.03.140