Technology Process of C40H50O5Si
There total 9 articles about C40H50O5Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
triethylsilane; boron trifluoride diethyl etherate;
In
dichloromethane;
at -78 ℃;
for 1.5h;
optical yield given as %de;
Inert atmosphere;
DOI:10.1021/ja804659n
- Guidance literature:
-
Multi-step reaction with 8 steps
1.1: 89 percent / 2,2-di(S-4-tBu-4,5-dihydrooxazol-2-yl)propane Cu(II) complex / CH2Cl2 / 12 h
2.1: 98 percent / Me3Al / tetrahydrofuran
3.1: 95 percent / NaH / dimethylformamide
4.1: 90 percent / tBuLi / diethyl ether / -78 °C
5.1: L-Selectride / tetrahydrofuran / -78 °C
6.1: O3; pyridine / CH2Cl2; methanol / -78 °C
6.2: Me2S / CH2Cl2; methanol / -78 - 20 °C
7.1: pyridinium p-toluenesulfonate
8.1: Et3SiH; BF3*OEt2 / CH2Cl2 / -78 °C
With
pyridine; triethylsilane; boron trifluoride diethyl etherate; trimethylaluminum; tert.-butyl lithium; pyridinium p-toluenesulfonate; L-Selectride; sodium hydride; ozone;
2,2-di(S-4-tBu-4,5-dihydrooxazol-2-yl)propane Cu(II) complex;
In
tetrahydrofuran; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1002/anie.200701515
- Guidance literature:
-
With
triethylsilane; boron trifluoride diethyl etherate;
In
dichloromethane;
at -78 ℃;
DOI:10.1002/anie.200701515