(E)-2-Methyl-1-(phenyldimethylsilyl)-4-<(p-toluenesulfonyl)oxy>-1-butene

Base Information

Chemical Name:(E)-2-Methyl-1-(phenyldimethylsilyl)-4-<(p-toluenesulfonyl)oxy>-1-butene
CAS No.:168132-13-6
Molecular Formula:C₂₀H₂₆O₃SSi
Molecular Weight:374.576
Hs Code.:

Synonyms:(E)-2-Methyl-1-(phenyldimethylsilyl)-4-<(p-toluenesulfonyl)oxy>-1-butene

Suppliers and Price of (E)-2-Methyl-1-(phenyldimethylsilyl)-4-<(p-toluenesulfonyl)oxy>-1-butene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-2-Methyl-1-(phenyldimethylsilyl)-4-<(p-toluenesulfonyl)oxy>-1-butene

Chemical Property:

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Technology Process of (E)-2-Methyl-1-(phenyldimethylsilyl)-4-<(p-toluenesulfonyl)oxy>-1-butene

There total 3 articles about (E)-2-Methyl-1-(phenyldimethylsilyl)-4-<(p-toluenesulfonyl)oxy>-1-butene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 168132-12-5
(E)-2-Methyl-1-(phenyldimethylsilyl)-1-buten-4-ol

: 98-59-9
p-toluenesulfonyl chloride

: 168132-13-6
(E)-2-Methyl-1-(phenyldimethylsilyl)-4-<(p-toluenesulfonyl)oxy>-1-butene

Guidance literature:: With dmap; triethylamine; In dichloromethane; for 12h; Ambient temperature;
DOI:10.1021/jo00122a038

Reference yield:

: 168132-11-4
(E)-2-Methyl-1-(phenyldimethylsilyl)-4-(tetrahydropyranyloxy)-1-butene

: 168132-13-6
(E)-2-Methyl-1-(phenyldimethylsilyl)-4-<(p-toluenesulfonyl)oxy>-1-butene

Guidance literature:: Multi-step reaction with 2 steps

1: 97 percent / p-TsOH*H₂O / ethanol / 2 h / Ambient temperature

2: 86 percent / Et₃N, 4-(dimethylamino)pyridine / CH₂Cl₂ / 12 h / Ambient temperature

With dmap; toluene-4-sulfonic acid; triethylamine; In ethanol; dichloromethane;
DOI:10.1021/jo00122a038

Reference yield:

: 768-33-2
phenyldimethylsilyl chloride

: 168132-13-6
(E)-2-Methyl-1-(phenyldimethylsilyl)-4-<(p-toluenesulfonyl)oxy>-1-butene

Guidance literature:: Multi-step reaction with 3 steps

1: 97 percent / p-TsOH*H₂O / ethanol / 2 h / Ambient temperature

2: 86 percent / Et₃N, 4-(dimethylamino)pyridine / CH₂Cl₂ / 12 h / Ambient temperature

With dmap; toluene-4-sulfonic acid; triethylamine; In ethanol; dichloromethane;
DOI:10.1021/jo00122a038