di-μ-chloro-bis(6-methoxy-2-pyridyl)bis(triphenylphosphine)dinickel(II)

Base Information

Chemical Name:di-μ-chloro-bis(6-methoxy-2-pyridyl)bis(triphenylphosphine)dinickel(II)
CAS No.:73191-24-9
Molecular Formula:C₄₈H₄₂Cl₂N₂Ni₂O₂P₂
Molecular Weight:929.107
Hs Code.:

Synonyms:di-μ-chloro-bis(6-methoxy-2-pyridyl)bis(triphenylphosphine)dinickel(II)

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Chemical Property of di-μ-chloro-bis(6-methoxy-2-pyridyl)bis(triphenylphosphine)dinickel(II)

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Technology Process of di-μ-chloro-bis(6-methoxy-2-pyridyl)bis(triphenylphosphine)dinickel(II)

There total 1 articles about di-μ-chloro-bis(6-methoxy-2-pyridyl)bis(triphenylphosphine)dinickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 17228-64-7
6-chloro-2-methoxypyridine

: 15133-82-1
tetrakis(triphenylphosphine)nickel⁽⁰⁾

: 73191-24-9
di-μ-chloro-bis(6-methoxy-2-pyridyl)bis(triphenylphosphine)dinickel(II)

Guidance literature:: In toluene; dropwise addn. of 2-chloro-6-methoxypyridine to starting Ni complex soln. in toluene, stirring for 1 h, all at 25°C; filtration, washing with methanol, vac. drying, recrystn. (CH2Cl2/methanol), elem. anal.;
DOI:10.1246/bcsj.53.139

Reference yield: 90.0%

: 73191-24-9
di-μ-chloro-bis(6-methoxy-2-pyridyl)bis(triphenylphosphine)dinickel(II)

: 73231-10-4
[Ni(NCS)(CH₃OC₅H₃N)(P(C₆H₅)3)]2

Guidance literature:: With NaSCN; In methanol; dichloromethane; dissolving of starting Ni complex in CH2Cl2, slow addn. of methanol, dropwise addn. of NaSCN methanol soln., stirring for 2 h at 25°C; vac. concn., recrystn. (CH2Cl2/methanol), elem. anal.;
DOI:10.1246/bcsj.53.139

Reference yield: 75.0%

: 73191-24-9
di-μ-chloro-bis(6-methoxy-2-pyridyl)bis(triphenylphosphine)dinickel(II)

: [Ni(NCO)(CH₃OC₅H₃N)(P(C₆H₅)3)]2

Guidance literature:: With NaOCN; In methanol; dichloromethane; dissolving of starting Ni complex in CH2Cl2, slow addn. of methanol, dropwise addn. of NaOCN aq. methanol soln., stirring for 2 h at 25°C (NaOCN was initially dissolved in water, then methanol added); vac. concn., recrystn. (CH2Cl2/methanol), elem. anal.;
DOI:10.1246/bcsj.53.139