4-[(1E)-2-(4-iodophenyl)ethenyl]-N,N-dioctylbenzenamine

Base Information

• Chemical Name: 4-[(1E)-2-(4-iodophenyl)ethenyl]-N,N-dioctylbenzenamine
• CAS No.: 933037-93-5
• Molecular Formula: C₃₀H₄₄IN
• Molecular Weight: 545.591
• Mol file: 933037-93-5.mol

Synonyms:4-[(1E)-2-(4-iodophenyl)ethenyl]-N,N-dioctylbenzenamine

Chemical Property of 4-[(1E)-2-(4-iodophenyl)ethenyl]-N,N-dioctylbenzenamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-[(1E)-2-(4-iodophenyl)ethenyl]-N,N-dioctylbenzenamine

There total 6 articles about 4-[(1E)-2-(4-iodophenyl)ethenyl]-N,N-dioctylbenzenamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

p-(iodophenyl)carboxaldehyde (15164-44-0) + {[4-(dioctylamino)phenyl]methyl}triphenylphosphonium iodide → 4-[(1E)-2-(4-iodophenyl)ethenyl]-N,N-dioctylbenzenamine (933037-93-5)

Guidance literature:

p-(iodophenyl)carboxaldehyde; {[4-(dioctylamino)phenyl]methyl}triphenylphosphonium iodide; With potassium tert-butylate; In dichloromethane; at 20 ℃; for 5h;

With iodine; In dichloromethane; for 2h; Further stages.; Irradiation;

DOI:10.1021/ol017150e

Reference yield: 75.0%

4-(dioctylamino)benzyltriphenyl phosphonium bromide + p-(iodophenyl)carboxaldehyde (15164-44-0) → 4-[(1E)-2-(4-iodophenyl)ethenyl]-N,N-dioctylbenzenamine (933037-93-5)

Guidance literature:

4-(dioctylamino)benzyltriphenyl phosphonium bromide; p-(iodophenyl)carboxaldehyde; With 18-crown-6 ether; sodium hydride; In tetrahydrofuran; at 20 ℃;

With iodine; In dichloromethane; at 20 ℃; Irradiation;

DOI:10.1002/asia.201000681

Reference yield:

N,N-dioctylaminobenzene (3007-75-8) → 4-[(1E)-2-(4-iodophenyl)ethenyl]-N,N-dioctylbenzenamine (933037-93-5)

Guidance literature:

Multi-step reaction with 2 steps

1.1: 78 percent / NaI / CHCl₃; acetic acid; H₂O / 24 h / Heating

2.1: t-BuOK / CH₂Cl₂ / 5 h / 20 °C

2.2: 85 percent / I₂ / CH₂Cl₂ / 2 h / Irradiation

With potassium tert-butylate; sodium iodide; In dichloromethane; chloroform; water; acetic acid; 2.1: Wittig reaction;

DOI:10.1021/ol017150e

upstream raw materials:

p-(iodophenyl)carboxaldehyde

4-[2-(4-iodophenyl)ethenyl]-N,N-dioctylbenzenamine

N,N-dioctylaminobenzene

Downstream raw materials:

C₅₀H₅₈NOP

C₅₀H₅₈NPS

C₁₁₄H₁₄₄N₃PS

C₁₁₄H₁₄₄N₃OP