1-[dicarbonyl(η(5)-cyclopentadienyl)ferrio]-1,1-dimethyl-3,3-bis(4-methylphenyl)disiloxane

Base Information

Chemical Name:1-[dicarbonyl(η(5)-cyclopentadienyl)ferrio]-1,1-dimethyl-3,3-bis(4-methylphenyl)disiloxane
CAS No.:506440-68-2
Molecular Formula:C₂₃H₂₆FeO₃Si₂
Molecular Weight:462.476
Hs Code.:

Synonyms:1-[dicarbonyl(η(5)-cyclopentadienyl)ferrio]-1,1-dimethyl-3,3-bis(4-methylphenyl)disiloxane

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Chemical Property of 1-[dicarbonyl(η(5)-cyclopentadienyl)ferrio]-1,1-dimethyl-3,3-bis(4-methylphenyl)disiloxane

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Technology Process of 1-[dicarbonyl(η(5)-cyclopentadienyl)ferrio]-1,1-dimethyl-3,3-bis(4-methylphenyl)disiloxane

There total 1 articles about 1-[dicarbonyl(η(5)-cyclopentadienyl)ferrio]-1,1-dimethyl-3,3-bis(4-methylphenyl)disiloxane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 140149-29-7
[dicarbonyl(η(5)-cyclopentadienyl)ferrio]dimethylsilanol

: 18551-61-6
chlorobis(4-methylphenyl)silane

: 506440-68-2
1-[dicarbonyl(η(5)-cyclopentadienyl)ferrio]-1,1-dimethyl-3,3-bis(4-methylphenyl)disiloxane

Guidance literature:: With Et₃N; In diethyl ether; byproducts: [Et3NH]Cl; under N2, Et2O soln. of Fe-comp. was treated with Et3N and chlorosilane,stirring at room temp. for 5 h; ppt. was filtered off, volatiles were removed in vac., residue was extd.with n-pentane, solvent was removed, dried in vac., elem. anal.;
DOI:10.1002/1099-0682(200212)2002:12<3235::AID-EJIC3235>3.0.CO;2-A

Reference yield: 10.0%

: 506440-68-2
1-[dicarbonyl(η(5)-cyclopentadienyl)ferrio]-1,1-dimethyl-3,3-bis(4-methylphenyl)disiloxane

: bis(μ-1,1-dimethyl-3,3-bis(4-methylphenyl)disiloxane-1,3-diyl)bis[carbonyl(η(5)-cyclopentadienyl)hydridoiron(IV)]

Guidance literature:: In cyclohexane; Irradiation (UV/VIS); under N2, irradn. with UV light for 20 h; solvent was removed in vac., chromy. (silica gel, 20 °C, cyclohexane/benzene=2:1), yellow zone was concd. to dryness, crystn. at -78 °C from pentane, elem. anal.;
DOI:10.1002/1099-0682(200212)2002:12<3235::AID-EJIC3235>3.0.CO;2-A