Technology Process of C43H60O7Si
There total 2 articles about C43H60O7Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride;
In
dichloromethane;
at 40 ℃;
for 14h;
DOI:10.1002/anie.200600295
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: nBuLi / hexane; tetrahydrofuran / 1 h / 0 °C
1.2: hexane; tetrahydrofuran / 18 h / -78 - 25 °C
2.1: 60 percent / Grubbs' catalyst II / CH2Cl2 / 14 h / 40 °C
With
n-butyllithium;
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride;
In
tetrahydrofuran; hexane; dichloromethane;
DOI:10.1002/anie.200600295
- Guidance literature:
-
Multi-step reaction with 4 steps
1: tetra-n-butylammonium fluoride / tetrahydrofuran / 14 h / 25 °C
2: (COCl)2; dimethyl sulfoxide; Et3N / CH2Cl2 / -78 - 0 °C
3: NaClO2; NaH2PO4; 2-methyl-2-butene / 2-methyl-propan-2-ol; H2O / 1 h / 25 °C
4: dicyclohexylcarbodiimide / CH2Cl2 / 2 h / 25 °C
With
sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; oxalyl dichloride; tetrabutyl ammonium fluoride; dimethyl sulfoxide; triethylamine; dicyclohexyl-carbodiimide;
In
tetrahydrofuran; dichloromethane; water; tert-butyl alcohol;
2: Swern oxidation;
DOI:10.1002/anie.200600295
