(3S,4R,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-methoxy-tetrahydro-pyran-3-ol

Base Information

Chemical Name:(3S,4R,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-methoxy-tetrahydro-pyran-3-ol
CAS No.:158719-06-3
Molecular Formula:C₂₂H₃₀O₄Si
Molecular Weight:386.563
Hs Code.:

Synonyms:(3S,4R,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-methoxy-tetrahydro-pyran-3-ol

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Chemical Property of (3S,4R,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-methoxy-tetrahydro-pyran-3-ol

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Technology Process of (3S,4R,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-methoxy-tetrahydro-pyran-3-ol

There total 3 articles about (3S,4R,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-methoxy-tetrahydro-pyran-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: 26528-46-1
methyl β-2-deoxy-L-ribopyranoside

: 158719-06-3
(3S,4R,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-methoxy-tetrahydro-pyran-3-ol

Guidance literature:: With pyridine; silver nitrate; In tetrahydrofuran; at 23 ℃; for 3h;
DOI:10.1021/ja00091a004

Reference yield:

: 20535-30-2
C₂₀H₁₈N₂O₁₀

: 158719-06-3
(3S,4R,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-methoxy-tetrahydro-pyran-3-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / 25percent methanolic NaOMe / 1 h / 23 °C

2: 68 percent / pyridine, AgNO₃ / tetrahydrofuran / 3 h / 23 °C

With pyridine; sodium methylate; silver nitrate; In tetrahydrofuran;
DOI:10.1021/ja00091a004

Reference yield:

: 17676-20-9
methyl 2-deoxy-β-D-erythro-pentopyranoside

: 158719-06-3
(3S,4R,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-methoxy-tetrahydro-pyran-3-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 50 percent / diethyl azodicarboxylate, PPh₃ / ethyl acetate / 4 h / 50 °C

2: 90 percent / 25percent methanolic NaOMe / 1 h / 23 °C

3: 68 percent / pyridine, AgNO₃ / tetrahydrofuran / 3 h / 23 °C

With pyridine; sodium methylate; silver nitrate; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; ethyl acetate;
DOI:10.1021/ja00091a004