(2S,3R)-1,3-[(S)-benzylidenedioxy]-5-(triisopropylsiloxy)-2-methylpentane

Base Information

Chemical Name:(2S,3R)-1,3-[(S)-benzylidenedioxy]-5-(triisopropylsiloxy)-2-methylpentane
CAS No.:873436-71-6
Molecular Formula:C₂₂H₃₈O₃Si
Molecular Weight:378.627
Hs Code.:

Synonyms:(2S,3R)-1,3-[(S)-benzylidenedioxy]-5-(triisopropylsiloxy)-2-methylpentane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,3R)-1,3-[(S)-benzylidenedioxy]-5-(triisopropylsiloxy)-2-methylpentane

Chemical Property:

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Technology Process of (2S,3R)-1,3-[(S)-benzylidenedioxy]-5-(triisopropylsiloxy)-2-methylpentane

There total 1 articles about (2S,3R)-1,3-[(S)-benzylidenedioxy]-5-(triisopropylsiloxy)-2-methylpentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: (3R,4S)-3,5-[(S)-benzylidenedioxy]-4-methylpentanol

: 13154-24-0
triisopropylsilyl chloride

: 873436-71-6
(2S,3R)-1,3-[(S)-benzylidenedioxy]-5-(triisopropylsiloxy)-2-methylpentane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; for 3h;
DOI:10.1002/chem.200500417

Reference yield: 90.0%

: 873436-71-6
(2S,3R)-1,3-[(S)-benzylidenedioxy]-5-(triisopropylsiloxy)-2-methylpentane

: 873436-73-8
(2S,3R)-3-benzyloxy-5-(triisopropylsiloxy)-2-methylpentanol

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; at 0 ℃; for 2h;
DOI:10.1002/chem.200500417

Reference yield:

: 873436-71-6
(2S,3R)-1,3-[(S)-benzylidenedioxy]-5-(triisopropylsiloxy)-2-methylpentane

: 873436-74-9
(3R,4R)-3-benzyloxy-1-(triisopropylsiloxy)-5-iodo-4-methylpentanol

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / DIBAL / CH₂Cl₂ / 2 h / 0 °C

2: 95 percent / imidazole; PPh₃; I₂ / benzene / 0.5 h / 20 °C

With 1H-imidazole; iodine; diisobutylaluminium hydride; triphenylphosphine; In dichloromethane; benzene;
DOI:10.1002/chem.200500417