(Z)-methyl 4-(3-chlorophenyl)-2-diazo-3-(isopropoxyimino)butanoate

Base Information

• Chemical Name: (Z)-methyl 4-(3-chlorophenyl)-2-diazo-3-(isopropoxyimino)butanoate
• CAS No.: 1318796-47-2
• Molecular Formula: C₁₄H₁₆ClN₃O₃
• Molecular Weight: 309.752
• Mol file: 1318796-47-2.mol

Synonyms:(Z)-methyl 4-(3-chlorophenyl)-2-diazo-3-(isopropoxyimino)butanoate

Chemical Property of (Z)-methyl 4-(3-chlorophenyl)-2-diazo-3-(isopropoxyimino)butanoate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (Z)-methyl 4-(3-chlorophenyl)-2-diazo-3-(isopropoxyimino)butanoate

There total 1 articles about (Z)-methyl 4-(3-chlorophenyl)-2-diazo-3-(isopropoxyimino)butanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

methyl 4-(3-chlorophenyl)-3-(isopropoxyimino)butanoate → (Z)-methyl 4-(3-chlorophenyl)-2-diazo-3-(isopropoxyimino)butanoate (1318796-47-2)

Guidance literature:

With p-nitrobenzenesulfonyl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene; In acetonitrile; at -20 ℃; for 2h; Inert atmosphere;

DOI:10.1039/c1cc11683e

Reference yield: 21.0%

(Z)-methyl 4-(3-chlorophenyl)-2-diazo-3-(isopropoxyimino)butanoate (1318796-47-2) → methyl 3-(3-chlorobenzyl)-2H-azirine-2-carboxylate + methyl 3-(3-chlorobenzyl)-5,5-dimethyl-4,5-dihydroisoxazole-4-carboxylate (1318796-66-5)

Guidance literature:

With rhodium(II) pivalate; In 1,2-dichloro-ethane; at 20 ℃; Inert atmosphere;

DOI:10.1039/c1cc11683e

Downstream raw materials:

methyl 3-(3-chlorobenzyl)-5,5-dimethyl-4,5-dihydroisoxazole-4-carboxylate