(-)-(3S,4S,6S,8R,10S)-4-methoxybenzyl 3-hydroxy-4,6,8,10-tetramethyl-11-(tetrahydro-2H-pyran-2-yloxy)undecanoate

Base Information

Chemical Name:(-)-(3S,4S,6S,8R,10S)-4-methoxybenzyl 3-hydroxy-4,6,8,10-tetramethyl-11-(tetrahydro-2H-pyran-2-yloxy)undecanoate
CAS No.:1259491-27-4
Molecular Formula:C₂₈H₄₆O₆
Molecular Weight:478.67
Hs Code.:

Synonyms:(-)-(3S,4S,6S,8R,10S)-4-methoxybenzyl 3-hydroxy-4,6,8,10-tetramethyl-11-(tetrahydro-2H-pyran-2-yloxy)undecanoate

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Chemical Property of (-)-(3S,4S,6S,8R,10S)-4-methoxybenzyl 3-hydroxy-4,6,8,10-tetramethyl-11-(tetrahydro-2H-pyran-2-yloxy)undecanoate

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Technology Process of (-)-(3S,4S,6S,8R,10S)-4-methoxybenzyl 3-hydroxy-4,6,8,10-tetramethyl-11-(tetrahydro-2H-pyran-2-yloxy)undecanoate

There total 1 articles about (-)-(3S,4S,6S,8R,10S)-4-methoxybenzyl 3-hydroxy-4,6,8,10-tetramethyl-11-(tetrahydro-2H-pyran-2-yloxy)undecanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1259491-26-3
(-)-(4S,6S,8R,10S)-4-methoxybenzyl 4,6,8,10-tetramethyl-3-oxo-11-(tetrahydro-2H-pyran-2-yloxy)undecanoate

: 1259491-27-4
(-)-(3S,4S,6S,8R,10S)-4-methoxybenzyl 3-hydroxy-4,6,8,10-tetramethyl-11-(tetrahydro-2H-pyran-2-yloxy)undecanoate

Guidance literature:: With (R)-[(RuCl(Tol-BINAP))2(μ-Cl)3*NH2Me2]; hydrogen; In ethanol; at 20 ℃; for 8h; under 3750.38 Torr; optical yield given as %de; diastereoselective reaction;
DOI:10.1002/chem.201001284