tert-butyldiphenylsilyl 2-azido-3,6-di-O-benzyl-2-deoxy-β-D-dlucopyranoside

Base Information

• Chemical Name: tert-butyldiphenylsilyl 2-azido-3,6-di-O-benzyl-2-deoxy-β-D-dlucopyranoside
• CAS No.: 144914-16-9
• Molecular Formula: C₃₆H₄₁N₃O₅Si
• Molecular Weight: 623.824
• Mol file: 144914-16-9.mol

Synonyms:tert-butyldiphenylsilyl 2-azido-3,6-di-O-benzyl-2-deoxy-β-D-dlucopyranoside

Chemical Property of tert-butyldiphenylsilyl 2-azido-3,6-di-O-benzyl-2-deoxy-β-D-dlucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of tert-butyldiphenylsilyl 2-azido-3,6-di-O-benzyl-2-deoxy-β-D-dlucopyranoside

There total 1 articles about tert-butyldiphenylsilyl 2-azido-3,6-di-O-benzyl-2-deoxy-β-D-dlucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

tert-butyldiphenylsilyl 2-azido-2-dedeoxy-3-O-benzylidene-β-D-glucopyranoside → tert-butyldiphenylsilyl 2-azido-3,6-di-O-benzyl-2-deoxy-β-D-dlucopyranoside (144914-16-9)

Guidance literature:

With 4 A molecular sieve; sodium cyanoborohydride; In tetrahydrofuran;

DOI:10.1016/S0008-6215(99)00313-4

Reference yield: 80.0%

tert-butyldiphenylsilyl 2-azido-3,6-di-O-benzyl-2-deoxy-β-D-dlucopyranoside (144914-16-9) + 1-bromo-1-deoxy-2,3,4,6-tetra-O-acetyl-a-D-galactopyranoside (3068-32-4) → tert-butyldiphenylsilyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->4)-2-azido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside (503830-93-1)

Guidance literature:

With silver trifluoromethanesulfonate;

DOI:10.1016/S0040-4039(02)01947-0

Reference yield: 75.0%

5-acetamido-4,7,8,9-tetra-O-benzyl-3,5-dideoxy-D-glycero-α-D-galacto-2-nanulopyranosylonic acid-(2->3)-2,6-di-O-benzyl-α-D-galactopyranosyl-trichloroacetamidate (1b->4a)-lactone (197630-86-7) + tert-butyldiphenylsilyl 2-azido-3,6-di-O-benzyl-2-deoxy-β-D-dlucopyranoside (144914-16-9) → tert-butyldiphenylsilyl 5-acetamido-4,7,8,9-tetra-O-benzyl-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonic acid-(2->3)-2,6-di-O-benzyl-D-galactopyranosyl-(1->4)-2-azido-2-deoxy-3,6-di-O-benzyl-β-D-glucopyranosisde-(1b->4a)-lactone (227286-38-6)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; In hexane; dichloromethane; at -40 ℃;

DOI:10.1016/S0040-4039(99)00605-X

Downstream raw materials:

tert-butyldiphenylsilyl 5-acetamido-4,7,8,9-tetra-O-benzyl-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonic acid-(2->3)-2,6-di-O-benzyl-D-galactopyranosyl-(1->4)-2-azido-2-deoxy-3,6-di-O-benzyl-β-D-glucopyranosisde-(1b->4a)-lactone

tert-butyldiphenylsilyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->4)-2-azido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside

tert-butyldiphenylsilyl 4,6-O-benzylidene-β-D-galactopyranosyl-(1->4)-2-azido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside

2,3-di-O-benzyl-4,6-O-benzylidene-β-D-galactopyranosyl-(1->4)-3,6-di-O-benzyl-2-deoxy-2-trichloroacetamido-α-D-glucopyranosyl fluoride