methyl 2-deoxy-6-O-(4-methoxyphenyl)-3,4-bis[2-(2-iodoethoxy)ethyl]-α-D-ribo-hexopyranoside

Base Information

Chemical Name:methyl 2-deoxy-6-O-(4-methoxyphenyl)-3,4-bis[2-(2-iodoethoxy)ethyl]-α-D-ribo-hexopyranoside
CAS No.:1417817-44-7
Molecular Formula:C₂₂H₃₄I₂O₈
Molecular Weight:680.316
Hs Code.:

Synonyms:methyl 2-deoxy-6-O-(4-methoxyphenyl)-3,4-bis[2-(2-iodoethoxy)ethyl]-α-D-ribo-hexopyranoside

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Chemical Property of methyl 2-deoxy-6-O-(4-methoxyphenyl)-3,4-bis[2-(2-iodoethoxy)ethyl]-α-D-ribo-hexopyranoside

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Technology Process of methyl 2-deoxy-6-O-(4-methoxyphenyl)-3,4-bis[2-(2-iodoethoxy)ethyl]-α-D-ribo-hexopyranoside

There total 5 articles about methyl 2-deoxy-6-O-(4-methoxyphenyl)-3,4-bis[2-(2-iodoethoxy)ethyl]-α-D-ribo-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 1417817-42-5
methyl 2-deoxy-6-O-(4-methoxyphenyl)-3,4-bis[2-(2-chloroethoxy)ethyl]-α-D-ribo-hexopyranoside

: 1417817-44-7
methyl 2-deoxy-6-O-(4-methoxyphenyl)-3,4-bis[2-(2-iodoethoxy)ethyl]-α-D-ribo-hexopyranoside

Guidance literature:: With sodium iodide; In acetone; for 40h; Reflux;
DOI:10.1016/j.carres.2012.10.020

Reference yield:

: 1417817-38-9
methyl 2-deoxy-6-O-(4-methoxyphenyl)-α-D-ribo-hexopyranoside

: 1417817-44-7
methyl 2-deoxy-6-O-(4-methoxyphenyl)-3,4-bis[2-(2-iodoethoxy)ethyl]-α-D-ribo-hexopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: tetra(n-butyl)ammonium hydrogensulfate; sodium hydride / water / 14 h / 20 °C

2: sodium iodide / acetone / 40 h / Reflux

With tetra(n-butyl)ammonium hydrogensulfate; sodium hydride; sodium iodide; In water; acetone;
DOI:10.1016/j.carres.2012.10.020

Reference yield:

: 6752-48-3,16718-95-9,18424-62-9,19877-02-2,22886-97-1,52153-29-4,52612-68-7,55331-65-2,64978-95-6,65725-24-8,66512-93-4,67968-51-8,72904-80-4,77481-69-7,131615-73-1,138663-49-7,151214-39-0
methyl 2-deoxy-4,6-O-benzylidene-α-D-ribo-hexopyranoside

: 1417817-44-7
methyl 2-deoxy-6-O-(4-methoxyphenyl)-3,4-bis[2-(2-iodoethoxy)ethyl]-α-D-ribo-hexopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: palladium on activated charcoal; hydrogen / dichloromethane; methanol / 3.5 h / 20 °C / 7500.75 Torr

2: triphenylphosphine; di-isopropyl azodicarboxylate / tetrahydrofuran / 42 h / Reflux; Inert atmosphere

3: tetra(n-butyl)ammonium hydrogensulfate; sodium hydride / water / 14 h / 20 °C

4: sodium iodide / acetone / 40 h / Reflux

With di-isopropyl azodicarboxylate; palladium on activated charcoal; hydrogen; tetra(n-butyl)ammonium hydrogensulfate; sodium hydride; triphenylphosphine; sodium iodide; In tetrahydrofuran; methanol; dichloromethane; water; acetone; 2: |Mitsunobu Displacement;
DOI:10.1016/j.carres.2012.10.020