Epichlorohydrin carbonate

Base Information

• Chemical Name: Epichlorohydrin carbonate
• CAS No.: 2463-45-8
• Deprecated CAS: 1173202-08-8
• Molecular Formula: C4H5 Cl O3
• Molecular Weight: 136.535
• Hs Code.: 2932999099
• Mol file: 2463-45-8.mol

Synonyms:Epichlorohydrin carbonate;NSC 76035;BRN 0111159;Carbonic acid, (chloromethyl)ethylene ester;CARBONIC ACID, CYCLIC 3-CHLOROPROPYLENE ESTER;SCHEMBL14890299;Carbonic acid, cyclic (chloromethyl)ethylene ester (7CI,8CI);LS-51949;Carbonic acid, cyclic (chloromethyl)ethylene ester

Chemical Property of Epichlorohydrin carbonate

Chemical Property:

• Vapor Pressure: 0.000456mmHg at 25°C
• Melting Point: <-40 °C
• Refractive Index: 1.4320 (estimate)
• Boiling Point: 290.1°Cat760mmHg
• Flash Point: 148.6°C
• PSA: 35.53000
• Density: 1.39g/cm³
• LogP: 0.76060
• XLogP3: 1.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 135.9927217
• Heavy Atom Count: 8
• Complexity: 104

Purity/Quality:

97% ^*data from raw suppliers

4-(Chloromethyl)-1,3-dioxolan-2-one ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1COC(=O)OC1Cl

Technology Process of Epichlorohydrin carbonate

There total 33 articles about Epichlorohydrin carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.5%

epichlorohydrin (106-89-8,24969-06-0,13403-37-7) → 4-chloromethyl-[1,3]dioxolan-2-one (2463-45-8)

Guidance literature:

With (2S)-N,N,N-2-trimethylethanaminium-3-(1H-imidazol-4-yl)propanoic acid hydroiodide; at 120 ℃; for 6h; under 7500.75 Torr; Pressure;

DOI:10.1039/c3cy00769c

Reference yield: 99.0%

carbon dioxide (124-38-9,18923-20-1) + Phenyl glycidyl ether (122-60-1,71031-02-2) → 4-chloromethyl-[1,3]dioxolan-2-one (2463-45-8)

Guidance literature:

With branched cationic polymer; In 1-methyl-pyrrolidin-2-one; at 100 ℃; for 12h;

DOI:10.1002/pola.24969

Reference yield: 93.0%

carbon dioxide (124-38-9,18923-20-1) + epichlorohydrin (106-89-8,24969-06-0,13403-37-7) → 4-chloromethyl-[1,3]dioxolan-2-one (2463-45-8) + 4‐(bromomethyl)‐1,3‐dioxolan‐2‐one

Guidance literature:

With C₂₆H₄₂N₅⁽³⁺⁾*3Br^(1-); In water; at 80 ℃; for 0.5h; under 11251.1 Torr; Autoclave;

DOI:10.1016/j.apcata.2013.12.027

upstream raw materials:

phosgene

3-monochloro-1,2-propanediol

methylammonium carbonate

epichlorohydrin

Downstream raw materials:

4H,4'H-4,4'-(2-hydroxy-propane-1,3-diyl)-bis-pyrido[3,2-b][1,4]oxazin-3-one

(2S,5R,6R)-6-(2,2-Dimethyl-5-oxo-4-phenyl-imidazolidin-1-yl)-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid 2-oxo-[1,3]dioxolan-4-ylmethyl ester

3-[4-[1-[4-(2,3-dihydroxypropoxy)phenyl]-1-methylethyl]phenoxy]propane-1,2-diol

3-chloro-2-hydroxypropyl N-(2-vinyloxyethyl)carbamate