Ti(η(5)-C5Me4-p-C6H4F)2(η(2)-bis(trimethylsilyl)ethyne)

Base Information

Chemical Name:Ti(η(5)-C5Me4-p-C6H4F)2(η(2)-bis(trimethylsilyl)ethyne)
CAS No.:340037-46-9
Molecular Formula:C₃₈H₅₀F₂Si₂Ti
Molecular Weight:648.863
Hs Code.:

Synonyms:Ti(η(5)-C5Me4-p-C6H4F)2(η(2)-bis(trimethylsilyl)ethyne)

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Chemical Property of Ti(η(5)-C5Me4-p-C6H4F)2(η(2)-bis(trimethylsilyl)ethyne)

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Technology Process of Ti(η(5)-C5Me4-p-C6H4F)2(η(2)-bis(trimethylsilyl)ethyne)

There total 1 articles about Ti(η(5)-C5Me4-p-C6H4F)2(η(2)-bis(trimethylsilyl)ethyne) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 238421-85-7
Ti(η(5)-C5Me4-p-C6H4F)2Cl2

: 14630-40-1
Bis(trimethylsilyl)ethyne

: 340037-46-9
Ti(η(5)-C5Me4-p-C6H4F)2(η(2)-bis(trimethylsilyl)ethyne)

Guidance literature:: With Mg; In tetrahydrofuran; byproducts: MgCl2; all manipulations in vacuum using all-sealed glass devices equipprd withbreakable seals; Ti complex was degassed and mixed with activated magne sium, BTMSE and THF; stirred at 60°C until the red colour turned yellow and for further 30 min; soln. sepd. from unreacted Mg, evapd., extd. with hexane; allowed to stand overnight, grey powder (largely MgCl2) sepd. off; remaining yellow soln. concd., yellow crystals isolated; identified by single crystal X-raydiffraction;
DOI:10.1016/S0022-328X(00)00784-1

Reference yield: 19.0%

: 340037-46-9
Ti(η(5)-C5Me4-p-C6H4F)2(η(2)-bis(trimethylsilyl)ethyne)

: 340037-49-2
Ti(η(5)-C5Me4(p-C6H4F))(η(3):η(4)-C5Me2(p-C6H4F)2(CH2)2)

Guidance literature:: In m-xylene; byproducts: (E)- and (Z)-1,2-bis(trimethylsilyl)ethene, bis(trimethylsilyl)ethyne; Irradiation (UV/VIS); Ti complex was heated in m-xylene in a sealed ampoule to 150°C for 3 h; initially yellow mixt. turned to dirty-green; evapd., residue dissolved in warm hexane and left to stand overnight forcrystallization, blue solid sepd. off and recrystd. from warm hexane;
DOI:10.1016/S0022-328X(00)00784-1