Benzoic acid (5R,6R)-5-acetoxy-7-((2S,3R)-2,3-diacetoxy-tetrahydro-pyran-2-yl)-6-methyl-heptyl ester

Base Information

Chemical Name:Benzoic acid (5R,6R)-5-acetoxy-7-((2S,3R)-2,3-diacetoxy-tetrahydro-pyran-2-yl)-6-methyl-heptyl ester
CAS No.:82599-14-2
Molecular Formula:C₂₆H₃₆O₉
Molecular Weight:492.566
Hs Code.:

Synonyms:Benzoic acid (5R,6R)-5-acetoxy-7-((2S,3R)-2,3-diacetoxy-tetrahydro-pyran-2-yl)-6-methyl-heptyl ester

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Chemical Property of Benzoic acid (5R,6R)-5-acetoxy-7-((2S,3R)-2,3-diacetoxy-tetrahydro-pyran-2-yl)-6-methyl-heptyl ester

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Technology Process of Benzoic acid (5R,6R)-5-acetoxy-7-((2S,3R)-2,3-diacetoxy-tetrahydro-pyran-2-yl)-6-methyl-heptyl ester

There total 6 articles about Benzoic acid (5R,6R)-5-acetoxy-7-((2S,3R)-2,3-diacetoxy-tetrahydro-pyran-2-yl)-6-methyl-heptyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 82614-15-1
(2S,3R)-3-[(1R,2R)-2,6-Bis-(tert-butyl-dimethyl-silanyloxy)-1-methyl-hexyl]-2-methyl-oxirane-2-carbaldehyde

: 82599-14-2
Benzoic acid (5R,6R)-5-acetoxy-7-((2S,3R)-2,3-diacetoxy-tetrahydro-pyran-2-yl)-6-methyl-heptyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: tetrahydrofuran / 25 h / -78 °C

2: imidazole

3: 1.) LiAlH₄, 2.) CrO₃-Py

6: 1.) 10-camphorsulfonic acid / 1.) CH₂Cl", MeOH

With 1H-imidazole; lithium aluminium tetrahydride; chromium trioxide-pyridine complex; (1S)-10-camphorsulfonic acid; In tetrahydrofuran;
DOI:10.1021/ja00382a065

Reference yield:

: 82599-13-1
Benzoic acid (5R,6R)-5-(tert-butyl-dimethyl-silanyloxy)-6-{(2R,3S)-3-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-butyl]-3-methyl-oxiranyl}-heptyl ester

: 82599-14-2
Benzoic acid (5R,6R)-5-acetoxy-7-((2S,3R)-2,3-diacetoxy-tetrahydro-pyran-2-yl)-6-methyl-heptyl ester

Guidance literature:: With (1S)-10-camphorsulfonic acid; Multistep reaction; 1.) CH2Cl", MeOH;
DOI:10.1021/ja00382a065

Reference yield:

: 82599-09-5
(S)-3-{(2S,3S)-3-[(1S,2S)-2,6-Bis-(tert-butyl-dimethyl-silanyloxy)-1-methyl-hexyl]-2-methyl-oxiranyl}-3-hydroxy-propionic acid ethyl ester

: 82599-14-2
Benzoic acid (5R,6R)-5-acetoxy-7-((2S,3R)-2,3-diacetoxy-tetrahydro-pyran-2-yl)-6-methyl-heptyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: imidazole

2: 1.) LiAlH₄, 2.) CrO₃-Py

5: 1.) 10-camphorsulfonic acid / 1.) CH₂Cl", MeOH

With 1H-imidazole; lithium aluminium tetrahydride; chromium trioxide-pyridine complex; (1S)-10-camphorsulfonic acid;
DOI:10.1021/ja00382a065