(E)-8-(3,5-dimethoxyphenyl)-5-methyl-5-octenal

Base Information

Chemical Name:(E)-8-(3,5-dimethoxyphenyl)-5-methyl-5-octenal
CAS No.:153037-11-7
Molecular Formula:C₁₇H₂₄O₃
Molecular Weight:276.376
Hs Code.:

Synonyms:(E)-8-(3,5-dimethoxyphenyl)-5-methyl-5-octenal

Suppliers and Price of (E)-8-(3,5-dimethoxyphenyl)-5-methyl-5-octenal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-8-(3,5-dimethoxyphenyl)-5-methyl-5-octenal

Chemical Property:

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Technology Process of (E)-8-(3,5-dimethoxyphenyl)-5-methyl-5-octenal

There total 8 articles about (E)-8-(3,5-dimethoxyphenyl)-5-methyl-5-octenal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 153037-10-6
(E)-8-(3,5-dimethoxyphenyl)-5-methyloct-5-enenitrile

: 153037-11-7
(E)-8-(3,5-dimethoxyphenyl)-5-methyl-5-octenal

Guidance literature:: With diisobutylaluminium hydride; In benzene; for 14h; Ambient temperature;
DOI:10.1021/jo00079a045

Reference yield:

: 147663-61-4,29584-66-5
trans-3-(3,5-dimethoxyphenyl)-2-propen-1-ol

: 153037-11-7
(E)-8-(3,5-dimethoxyphenyl)-5-methyl-5-octenal

Guidance literature:: Multi-step reaction with 7 steps

1: 1.) DMSO, oxalyl chloride, 2.) Et₃N / 1.) CH₂Cl₂, -60 deg C, 2 min, 2.) CH₂Cl₂, 5 min

3: 82 percent / propionic acid / 3 h / 140 °C

4: LiAlH₄ / diethyl ether / 2 h / Ambient temperature

5: Ph₃P, CBr₄ / diethyl ether / 8 h / Ambient temperature

6: 88 percent / DMSO / 2 h / 50 °C

7: 63 percent / DIBAL-H / benzene / 14 h / Ambient temperature

With lithium aluminium tetrahydride; oxalyl dichloride; carbon tetrabromide; diisobutylaluminium hydride; dimethyl sulfoxide; propionic acid; triethylamine; triphenylphosphine; In diethyl ether; benzene;
DOI:10.1021/jo00079a045

Reference yield:

: 42174-79-8,29584-64-3
(E)-ethyl 3-(3,5-dimethoxyphenyl)acrylate

: 153037-11-7
(E)-8-(3,5-dimethoxyphenyl)-5-methyl-5-octenal

Guidance literature:: Multi-step reaction with 8 steps

1: LiAlH₄ / tetrahydrofuran / 6 h / Heating

2: 1.) DMSO, oxalyl chloride, 2.) Et₃N / 1.) CH₂Cl₂, -60 deg C, 2 min, 2.) CH₂Cl₂, 5 min

4: 82 percent / propionic acid / 3 h / 140 °C

5: LiAlH₄ / diethyl ether / 2 h / Ambient temperature

6: Ph₃P, CBr₄ / diethyl ether / 8 h / Ambient temperature

7: 88 percent / DMSO / 2 h / 50 °C

8: 63 percent / DIBAL-H / benzene / 14 h / Ambient temperature

With lithium aluminium tetrahydride; oxalyl dichloride; carbon tetrabromide; diisobutylaluminium hydride; dimethyl sulfoxide; propionic acid; triethylamine; triphenylphosphine; In tetrahydrofuran; diethyl ether; benzene;
DOI:10.1021/jo00079a045