phenyl O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→6)-2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside

Base Information

• Chemical Name: phenyl O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→6)-2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside
• CAS No.: 914102-32-2
• Molecular Formula: C₆₇H₆₂O₁₃S
• Molecular Weight: 1107.29

Synonyms:phenyl O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→6)-2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside

Chemical Property of phenyl O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→6)-2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenyl O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→6)-2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside

There total 5 articles about phenyl O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→6)-2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate (74808-09-6) + phenyl 2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside → phenyl O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→6)-2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside (914102-32-2)

Guidance literature:

With oligomeric (salen)Co complex; In acetonitrile; at 20 ℃; for 2h; stereoselective reaction; Inert atmosphere;

DOI:10.1039/c5cc02552d

Reference yield:

phenyl 2,3,4,5-tetra-O-benzyl-1-thio-β-D-glucopyranoside (38184-10-0) + phenyl 2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside → phenyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1→6)-2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside (1384861-27-1) + phenyl O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→6)-2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside (914102-32-2)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; (((2-(2-iodophenyl)propan-2-yl)oxy)(trifluoromethyl)sulfane); In dichloromethane; at -40 - 20 ℃; for 1.5h; Overall yield = 62 %; Overall yield = 69 mg; chemoselective reaction; Inert atmosphere; Molecular sieve;

DOI:10.1021/ol501211z

Reference yield:

O-(O2,O3,O4-tribenzyl-O6-triisopropylsilyl-α-D-glucopyranosyl) trichloroacetimidate + phenyl 2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside → phenyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1→6)-2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside (1384861-27-1) + phenyl O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→6)-2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside (914102-32-2)

Guidance literature:

With eosin Y; diphenyldisulfane; In dichloromethane; at 20 ℃; Overall yield = 81 percent; Overall yield = 179 mg; Sealed tube; Irradiation;

DOI:10.1039/d1cc04887b

upstream raw materials:

2-thiazolinyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside

2-allylphenyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside

phenyl 2,3,4,5-tetra-O-benzyl-1-thio-β-D-glucopyranoside

2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 914102-32-2 phenyl O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→6)-2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside

Send

Send

Metric Ton KG G Pound L ML

Send

Send