pseudopterolide

Base Information

• Chemical Name: pseudopterolide
• CAS No.: 83560-98-9
• Molecular Formula: C21H22 O6
• Molecular Weight: 370.402
• Mol file: 83560-98-9.mol

Synonyms:3,13,16-Trioxatetracyclo[10.2.1.17,10.02,4]hexadeca-1(15),7,9-triene-8-carboxylicacid, 5,11-bis(1-methylethenyl)-14-oxo-, methyl ester,[2S-(2R*,4S*,5S*,11S*,12S*)]-; NSC 344015; Pseudopterolide

Chemical Property of pseudopterolide

Chemical Property:

• Vapor Pressure: 3.02E-13mmHg at 25°C
• Boiling Point: 575.5°C at 760 mmHg
• Flash Point: 301.8°C
• PSA: 78.27000
• Density: 1.26g/cm³
• LogP: 3.09350

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of pseudopterolide

There total 1 articles about pseudopterolide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

((Z)-(2R,3S,8S,9R,15R)-8-Hydroxy-2,9-diisopropenyl-12-methoxycarbonyl-5-oxo-4,14-dioxa-tricyclo[9.2.1.13,6]pentadeca-1(13),6,11-trien-15-yl)-trimethyl-ammonium; iodide (132216-50-3) → Pseudopterolide (83560-98-9)

Guidance literature:

With sodium hydride; In 1,2-dimethoxyethane; for 0.333333h; Yield given; Ambient temperature;

DOI:10.1016/S0040-4039(00)97102-8

Reference yield: 48.0%

Pseudopterolide (83560-98-9) + thiophenol (108-98-5) → (2R,3S,6R,7S,8R,9R,15R)-8-Hydroxy-2,9-diisopropenyl-5-oxo-7,15-bis-phenylsulfanyl-4,14-dioxa-tricyclo[9.2.1.13,6]pentadeca-1(13),11-diene-12-carboxylic acid methyl ester

Guidance literature:

With triethylamine; In methanol; for 0.5h; Ambient temperature;

DOI:10.1016/S0040-4020(01)85501-0

Reference yield:

Ac-Cys-OMe (7652-46-2) + Pseudopterolide (83560-98-9) → (E)-(2R,3S,8S,9R,15R)-15-((S)-2-Acetylamino-2-methoxycarbonyl-ethylsulfanyl)-8-hydroxy-2,9-diisopropenyl-5-oxo-4,14-dioxa-tricyclo[9.2.1.13,6]pentadeca-1(13),6,11-triene-12-carboxylic acid methyl ester

Guidance literature:

With triethylamine; In methanol; for 0.5h; Ambient temperature;

DOI:10.1016/S0040-4020(01)85501-0

upstream raw materials:

((Z)-(2R,3S,8S,9R,15R)-8-Hydroxy-2,9-diisopropenyl-12-methoxycarbonyl-5-oxo-4,14-dioxa-tricyclo[9.2.1.1^3,6]pentadeca-1⁽¹³⁾,6,11-trien-15-yl)-trimethyl-ammonium; iodide