Sodium Imidazole

Base Information

• Chemical Name: Sodium Imidazole
• CAS No.: 5587-42-8
• Molecular Formula: C3H4N2Na
• Molecular Weight: 90.06
• Hs Code.: 29332990
• European Community (EC) Number: 226-988-5
• Nikkaji Number: J225.044F
• Mol file: 5587-42-8.mol

Synonyms:5587-42-8;Sodium Imidazole;Imidazole sodium derivative;sodium;imidazol-3-ide;Sodium imidazol-1-ide;Imidazole-I.J.K-(sodium derivative);sodium imidazolate;Sodiumimidazol-1-ide;imidazol-1-yl sodium;Imidazole, sodium salt;ITAWMPSVROAMOE-UHFFFAOYSA-N;MFCD00064314;Imidazole sodium derivative, technical grade

Chemical Property of Sodium Imidazole

Chemical Property:

• Appearance/Colour: Light yellow to orange free flowing crystalline
• Melting Point: 284 °C (dec.)(lit.)
• Boiling Point: 257 °C at 760 mmHg
• Flash Point: 145 °C
• PSA: 17.82000
• Density: 1.116 g/cm³
• LogP: 0.19550
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 90.01939239
• Heavy Atom Count: 6
• Complexity: 32

Purity/Quality:

99% ^*data from raw suppliers

Imidazole sodium derivative technical grade ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 20/21/22-34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CN=C[N-]1.[Na+]
• Uses: Imidazole sodium derivative (Imidazolylsodium) was used in the synthesis of arylazidoamorphigenin.

Technology Process of Sodium Imidazole

There total 7 articles about Sodium Imidazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.2%

1H-imidazole (288-32-4) → imidazolyl sodium (5587-42-8)

Guidance literature:

With sodium hydroxide; In water; chlorobenzene;

Reference yield:

1H-imidazole (288-32-4) + trans-6-[α-(2,4-dichlorobenzyl)-4-fluorobenzyloxy]-2-tosyloxymethyltetrahydropyran → 1-{6-[α-(2,4-dichlorobenzyl)-4-fluorobenzyloxy]tetrahydropyran-2-ylmethyl}imidazole + imidazolyl sodium (5587-42-8)

Guidance literature:

With sodium iodide; In N-methyl-acetamide;

Reference yield:

1H-imidazole (288-32-4) + 1-chloro-4-(4-methoxyphenyl)-2-butanol (59363-12-1) → 1-[2-hydroxy-4-(4-methoxyphenyl)-n-butyl]imidazole + imidazolyl sodium (5587-42-8)

Guidance literature:

In N-methyl-acetamide; hexane; water; mineral oil;

upstream raw materials:

1H-imidazole

1-chloro-4-(4-methoxyphenyl)-2-butanol

sodium hydride

Downstream raw materials:

N-vinylphthalimide

2-[2-(1H-imidazol-1-yl)ethyl]-isoindole-1,3(2H)-dione

1-hexyl-3-methyl-1-imidazolium bromide

di-tert-butyl nitroxide