(1S,5R)-2-exo,3-endo-dibenzoyloxy-6-oxo-4-exo-tosyloxybicyclo<3.2.0>heptane

Base Information

Chemical Name:(1S,5R)-2-exo,3-endo-dibenzoyloxy-6-oxo-4-exo-tosyloxybicyclo<3.2.0>heptane
CAS No.:88203-87-6
Molecular Formula:C₂₈H₂₄O₈S
Molecular Weight:520.56
Hs Code.:

Synonyms:(1S,5R)-2-exo,3-endo-dibenzoyloxy-6-oxo-4-exo-tosyloxybicyclo<3.2.0>heptane

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Chemical Property of (1S,5R)-2-exo,3-endo-dibenzoyloxy-6-oxo-4-exo-tosyloxybicyclo<3.2.0>heptane

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Technology Process of (1S,5R)-2-exo,3-endo-dibenzoyloxy-6-oxo-4-exo-tosyloxybicyclo<3.2.0>heptane

There total 4 articles about (1S,5R)-2-exo,3-endo-dibenzoyloxy-6-oxo-4-exo-tosyloxybicyclo<3.2.0>heptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 88203-86-5,88244-64-8
(1S,5S)-2-exo,3-endo-dibenzoyloxy-6-exo-hydroxy-4-exo-tosyloxybicyclo<3.2.0>heptane

: 88203-87-6
(1S,5R)-2-exo,3-endo-dibenzoyloxy-6-oxo-4-exo-tosyloxybicyclo<3.2.0>heptane

Guidance literature:: With dipyridinium dichromate; In dichloromethane; at 20 ℃; for 15h;

Reference yield:

: 88203-85-4
(1S,5S)-6-exo-acetoxy-2-exo,3-endo-dibenzoyloxy-4-exo-tosyloxybicyclo<3.2.0>heptane

: 88203-87-6
(1S,5R)-2-exo,3-endo-dibenzoyloxy-6-oxo-4-exo-tosyloxybicyclo<3.2.0>heptane

Guidance literature:: Multi-step reaction with 2 steps

1: 83 percent / aq. hydrogen chloride / tetrahydrofuran / 12 h / Heating

2: 95 percent / pyridinium dichromate / CH₂Cl₂ / 15 h / 20 °C

With hydrogenchloride; dipyridinium dichromate; In tetrahydrofuran; dichloromethane;

Reference yield:

: 88203-82-1
(1S,5S)-6-exo-acetyl-2-exo,3-endo-dibenzoyloxy-4-exo-tosyloxybicyclo<3.2.0>heptane

: 88203-87-6
(1S,5R)-2-exo,3-endo-dibenzoyloxy-6-oxo-4-exo-tosyloxybicyclo<3.2.0>heptane

Guidance literature:: Multi-step reaction with 3 steps

1: 85 percent / trifluoroperacetic acid, disodium hydrogen phosphate / CH₂Cl₂ / 15 h / 20 °C

2: 83 percent / aq. hydrogen chloride / tetrahydrofuran / 12 h / Heating

3: 95 percent / pyridinium dichromate / CH₂Cl₂ / 15 h / 20 °C

With hydrogenchloride; disodium hydrogenphosphate; dipyridinium dichromate; trifluoroacetyl peroxide; In tetrahydrofuran; dichloromethane;