bis[(5,5'-triisopropylsilylethynyl-10,20-di[4-(3-methoxy-3-methylbutoxy)phenyl]porphinato)zinc(II)]ethyne

Base Information

Chemical Name:bis[(5,5'-triisopropylsilylethynyl-10,20-di[4-(3-methoxy-3-methylbutoxy)phenyl]porphinato)zinc(II)]ethyne
CAS No.:402505-13-9
Molecular Formula:C₁₁₂H₁₂₆N₈O₈Si₂Zn₂
Molecular Weight:1899.23
Hs Code.:

Synonyms:bis[(5,5'-triisopropylsilylethynyl-10,20-di[4-(3-methoxy-3-methylbutoxy)phenyl]porphinato)zinc(II)]ethyne

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Chemical Property of bis[(5,5'-triisopropylsilylethynyl-10,20-di[4-(3-methoxy-3-methylbutoxy)phenyl]porphinato)zinc(II)]ethyne

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Technology Process of bis[(5,5'-triisopropylsilylethynyl-10,20-di[4-(3-methoxy-3-methylbutoxy)phenyl]porphinato)zinc(II)]ethyne

There total 1 articles about bis[(5,5'-triisopropylsilylethynyl-10,20-di[4-(3-methoxy-3-methylbutoxy)phenyl]porphinato)zinc(II)]ethyne which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 402505-33-3
(5-bromo-15-triisopropylsilylethynyl-10,20-di[4-(3-methoxy-3-methylbutoxy)phenyl]porphinato)zinc(II)

: 402505-09-3
(5-ethynyl-15-triisopropylsilylethynyl-10,20-di[4-(3-methoxy-3-methylbutoxy)phenyl]porphinato)zinc(II)

: 402505-13-9
bis[(5,5'-triisopropylsilylethynyl-10,20-di[4-(3-methoxy-3-methylbutoxy)phenyl]porphinato)zinc(II)]ethyne

Guidance literature:: With AsPh₃; triethyl amine; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In tetrahydrofuran; under N2, standard Schlenk techniques; THF and Et3N added to mixt. of Br-contg. Zn porphyrin, acetylene substituted Zn porphyrin, Pd2(dba)3 and AsPh3 (molar ratio 1.1:1:0.16:1.3); stirred (40°C, 4 h); solvent evapd.; purified by chromy. (silica gel, hexanes-THF); green-brown band isolated;
DOI:10.1021/ic010871p