<2S,3R(S)>-3-<3-(tert-butyldiphenylsilyloxy)propyl>-2-methyl-2-oxiranemethanol

Base Information

Chemical Name:<2S,3R(S)>-3-<3-(tert-butyldiphenylsilyloxy)propyl>-2-methyl-2-oxiranemethanol
CAS No.:142695-90-7
Molecular Formula:C₂₃H₃₂O₃Si
Molecular Weight:384.591
Hs Code.:

Synonyms:<2S,3R(S)>-3-<3-(tert-butyldiphenylsilyloxy)propyl>-2-methyl-2-oxiranemethanol

Suppliers and Price of <2S,3R(S)>-3-<3-(tert-butyldiphenylsilyloxy)propyl>-2-methyl-2-oxiranemethanol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of <2S,3R(S)>-3-<3-(tert-butyldiphenylsilyloxy)propyl>-2-methyl-2-oxiranemethanol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of <2S,3R(S)>-3-<3-(tert-butyldiphenylsilyloxy)propyl>-2-methyl-2-oxiranemethanol

There total 3 articles about <2S,3R(S)>-3-<3-(tert-butyldiphenylsilyloxy)propyl>-2-methyl-2-oxiranemethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 144604-72-8
(4S,2E)-5-(tert-butyldiphenylsilyloxy)-2,4-dimethylpent-2-en-1-ol

: 142695-90-7
<2S,3R(S)>-3-<3-(tert-butyldiphenylsilyloxy)propyl>-2-methyl-2-oxiranemethanol

Guidance literature:: With titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate; In dichloromethane; toluene; at -20 ℃;
DOI:10.1016/S0040-4020(01)80467-1

Reference yield:

: 91751-24-5,92817-88-4,123284-89-9,112897-04-8
(R)-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropanal

: 142695-90-7
<2S,3R(S)>-3-<3-(tert-butyldiphenylsilyloxy)propyl>-2-methyl-2-oxiranemethanol

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / CH₂Cl₂ / 5 h / Ambient temperature

2: 96 percent / Dibal-H / toluene / 0.5 h / -78 °C

3: 97 percent / D-(-)-diethyltartrate, Ti(OiPr)4, t-BuOOH / CH₂Cl₂; toluene / -20 °C

With titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate; diisobutylaluminium hydride; In dichloromethane; toluene;
DOI:10.1016/S0040-4020(01)80467-1

Reference yield:

: 142592-66-3
ethyl (2E,4S)-5-(tert-butyldiphenylsilyloxy)-2,4-dimethylpent-2-enoate

: 142695-90-7
<2S,3R(S)>-3-<3-(tert-butyldiphenylsilyloxy)propyl>-2-methyl-2-oxiranemethanol

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / Dibal-H / toluene / 0.5 h / -78 °C

2: 97 percent / D-(-)-diethyltartrate, Ti(OiPr)4, t-BuOOH / CH₂Cl₂; toluene / -20 °C

With titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate; diisobutylaluminium hydride; In dichloromethane; toluene;
DOI:10.1016/S0040-4020(01)80467-1