Technology Process of (Et4N)(PhCOW(CO)5)
There total 1 articles about (Et4N)(PhCOW(CO)5) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
CO;
In
dichloromethane;
under N2, soln. of W-complex stirred under CO at an initial pressure of312 torr, 7 days;
DOI:10.1021/ja00535a048
- Guidance literature:
-
With
oxalyl chloride;
In
dichloromethane;
(Ar); soln. of oxalyl chloride in CH2Cl2 was added to soln. of W complexin CH2Cl2 at -78°C; mixt. was warmed to -20°C over 2 h; c ooled to -78°C; salt of ligand was added; mixt. was warmed to 0°C over 2 h; solvent removed (vac.); residue suspnd. in CH2Cl2; chromd. (alumina, CH2Cl2); solvent evapd.; elem. anal.;
DOI:10.1016/S0022-328X(03)00044-5
- Guidance literature:
-
With
acetyl chloride;
In
dichloromethane;
(Ar); CH3COCl was added to soln. of carbene salt in CH2Cl2 at -40°C; stirred at -30°C for 45 min; cooled to -40°C; alcohol was added; warmed to 0°C over 2 h and stirred for 4 h; evapd. (vac.); dried (vac.); flash chromd.; elem. anal.;
DOI:10.1016/j.jorganchem.2005.07.042
![N(C<sub>2</sub>H<sub>5</sub>)4<sup>(1+)</sup>*W(C<sub>6</sub>H<sub>5</sub>)(CO)5<sup>(1-)</sup> = [N(C<sub>2</sub>H<sub>5</sub>)4][W(C<sub>6</sub>H<sub>5</sub>)(CO)5]](/Databaselist/images/loading.webp)
