Chlorodiphenylphosphine sulfide

Base Information

• Chemical Name: Chlorodiphenylphosphine sulfide
• CAS No.: 1015-37-8
• Molecular Formula: C12H10 Cl P S
• Molecular Weight: 252.704
• Hs Code.: 2930909090
• NSC Number: 46734
• DSSTox Substance ID: DTXSID90286639
• Nikkaji Number: J24.864I
• Wikidata: Q82022411
• Mol file: 1015-37-8.mol

Synonyms:Chlorodiphenylphosphine sulfide;Diphenylphosphinothioyl chloride;1015-37-8;Phosphinothioic chloride, diphenyl-;chloro-diphenyl-sulfanylidene-lambda5-phosphane;Diphenylphosphinothioic chloride;Diphenylchlorophosphine sulfide;Diphenylthiophosphinyl chloride;SCHEMBL2502559;DTXSID90286639;Diphenylthiophosphinochloridic acid;NSC46734;DIPHENYLPHOSPHINOTHIOYLCHLORIDE;NSC-46734

Chemical Property of Chlorodiphenylphosphine sulfide

Chemical Property:

• Vapor Pressure: 6.46E-05mmHg at 25°C
• Boiling Point: 355.3°Cat760mmHg
• Flash Point: 168.7°C
• PSA: 41.90000
• Density: 1.28g/cm³
• LogP: 3.92130
• XLogP3: 5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 251.9929362
• Heavy Atom Count: 15
• Complexity: 220

Purity/Quality:

98%,99%, ^*data from raw suppliers

DIPHENYLPHOSPHINOTHIOYL CHLORIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(=S)(C2=CC=CC=C2)Cl

Technology Process of Chlorodiphenylphosphine sulfide

There total 15 articles about Chlorodiphenylphosphine sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

Lawessons reagent (19172-47-5,94367-93-8) + Diphenylphosphinic chloride (1499-21-4) → diphenylthiophosphinoyl chloride (1015-37-8) + 2,4,6-tris(4-methoxyphenyl)-2,4,6-trisulfanylene-1,3,5,2,4,6-trioxatriphosphinane (137171-51-8,67218-02-4)

Guidance literature:

In benzene; for 1h; Heating;

Reference yield: 48.0%

diphenylphosphinodithioic acid (1015-38-9) + trichloroacetonitrile (545-06-2) → bis(diphenylphosphinothioyl)disulfide (6079-77-2) + diphenylthiophosphinoyl chloride (1015-37-8)

Guidance literature:

In diethyl ether; for 2h;

Reference yield: 33.0%

diphenyl-phosphinic acid (1707-03-5) → diphenylthiophosphinoyl chloride (1015-37-8)

Guidance literature:

With trichlorothiophosphine; Heating;

upstream raw materials:

diphenylphosphinodithioic acid

fluorobenzene

biphenyl

diphenyl-phosphinic acid

Downstream raw materials:

P,P-diphenylphosphinothioic amide

diphenylthiophosphinic acid

S-(1-Methyl-2-carbethoxy-vinyl)-diphenyl-dithiophosphinsaeureester

N,S-Bis(diphenylthiophosphinyl)-cysteamin