Technology Process of thiocarbonyl(2,3,7,8,12,13,17,18-octaethylporphinato)iron(II)
There total 2 articles about thiocarbonyl(2,3,7,8,12,13,17,18-octaethylporphinato)iron(II) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
iron;
In
methanol; dichloromethane;
Fe powder adding to a soln. of Fe(III) complex in CH2Cl2-MeOH, vigorously stirring for 15 min under Ar, ligand soln. in CH2Cl2 adding, stirringfor 2 h, filtering, evapg.; purified by recrystn. from CH2Cl2-MeOH; identified by elem. anal., UV, IR, mass and NMR spectra;
DOI:10.1021/ic00135a066
- Guidance literature:
-
With
1percent sodium amalgam;
In
tetrahydrofuran;
Ar; addn. of degassed THF soln. of the complex to 1% sodium amalgam, addn.of degased thiophosgene over 10 min, stirring for 24 h; decantation, washing the residue with THF, evapn. the combined soln. to dryness under vac., extn. with toluene, chromy. (neutral alumina), evapn. the solvent in vac. at 60°C, washing with hexane;
DOI:10.1021/ic030043r
- Guidance literature:
-
In
toluene;
slow evapn. concd. toluene soln. Fe(OEP)(CS);
DOI:10.1021/ic00133a065
