{N-[trans-2-(isoindolin-2-yl)-1,2-diphenylethyl]-[3,5-bis(tertbutyl)salicylaldiminate]}Ni^IICl

Base Information

• Chemical Name: {N-[trans-2-(isoindolin-2-yl)-1,2-diphenylethyl]-[3,5-bis(tertbutyl)salicylaldiminate]}Ni^IICl
• CAS No.: 1447273-31-5
• Molecular Formula: C₃₇H₄₁ClN₂NiO
• Molecular Weight: 623.888

Synonyms:{N-[trans-2-(isoindolin-2-yl)-1,2-diphenylethyl]-[3,5-bis(tertbutyl)salicylaldiminate]}Ni^IICl

Chemical Property of {N-[trans-2-(isoindolin-2-yl)-1,2-diphenylethyl]-[3,5-bis(tertbutyl)salicylaldiminate]}Ni^IICl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {N-[trans-2-(isoindolin-2-yl)-1,2-diphenylethyl]-[3,5-bis(tertbutyl)salicylaldiminate]}Ni^IICl

There total 5 articles about {N-[trans-2-(isoindolin-2-yl)-1,2-diphenylethyl]-[3,5-bis(tertbutyl)salicylaldiminate]}Ni^IICl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

bis(triphenylphosphine)nickel(II) chloride (14264-16-5,53996-95-5,62075-39-2,39716-73-9) + 4,6-di-tert-butyl-2-{(trans-2-(isoindolin-2-yl)-1,2-diphenylethylimino)methyl}phenol → {N-[trans-2-(isoindolin-2-yl)-1,2-diphenylethyl]-[3,5-bis(tertbutyl)salicylaldiminate]}NiIICl (1447273-31-5)

Guidance literature:

4,6-di-tert-butyl-2-{(trans-2-(isoindolin-2-yl)-1,2-diphenylethylimino)methyl}phenol; With sodium hydride; In tetrahydrofuran; at 0 - 20 ℃; for 2h;

bis(triphenylphosphine)nickel(II) chloride; In tetrahydrofuran; at 20 ℃; Schlenk technique;

DOI:10.1002/ejic.201201331

Reference yield:

rac-1,2-diphenylethylene-1,2-diamine (951-87-1,5700-60-7,16635-95-3,29841-69-8,35132-20-8,107133-00-6) → {N-[trans-2-(isoindolin-2-yl)-1,2-diphenylethyl]-[3,5-bis(tertbutyl)salicylaldiminate]}NiIICl (1447273-31-5)

Guidance literature:

Multi-step reaction with 5 steps

1.1: tetrahydrofuran / 72 h

2.1: N-ethyl-N,N-diisopropylamine / N,N-dimethyl-formamide / 48 h / 40 °C

3.1: ethanolamine / ethanol

4.1: ethanol / 20 °C / Schlenk technique; Molecular sieve; Inert atmosphere; Reflux

5.1: sodium hydride / tetrahydrofuran / 2 h / 0 - 20 °C

5.2: 20 °C / Schlenk technique

With sodium hydride; ethanolamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; ethanol; N,N-dimethyl-formamide; 4.1: |Schiff Reaction;

DOI:10.1002/ejic.201201331

Reference yield:

C22H24N4O3 (1207290-27-4) → {N-[trans-2-(isoindolin-2-yl)-1,2-diphenylethyl]-[3,5-bis(tertbutyl)salicylaldiminate]}NiIICl (1447273-31-5)

Guidance literature:

Multi-step reaction with 4 steps

1.1: N-ethyl-N,N-diisopropylamine / N,N-dimethyl-formamide / 48 h / 40 °C

2.1: ethanolamine / ethanol

3.1: ethanol / 20 °C / Schlenk technique; Molecular sieve; Inert atmosphere; Reflux

4.1: sodium hydride / tetrahydrofuran / 2 h / 0 - 20 °C

4.2: 20 °C / Schlenk technique

With sodium hydride; ethanolamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; ethanol; N,N-dimethyl-formamide; 3.1: |Schiff Reaction;

DOI:10.1002/ejic.201201331

upstream raw materials:

C₂₂H₂₄N₄O₃

rac-1,2-diphenylethylene-1,2-diamine

bis(triphenylphosphine)nickel(II) chloride

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 1447273-31-5 {N-[trans-2-(isoindolin-2-yl)-1,2-diphenylethyl]-[3,5-bis(tertbutyl)salicylaldiminate]}Ni^IICl

Send

Send

Metric Ton KG G Pound L ML

Send

Send