Acetic acid (2R,4aR,6S,8S,8aS)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester

Base Information

Chemical Name:Acetic acid (2R,4aR,6S,8S,8aS)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester
CAS No.:66512-94-5
Molecular Formula:C₁₆H₂₀O₆
Molecular Weight:308.331
Hs Code.:

Synonyms:Acetic acid (2R,4aR,6S,8S,8aS)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester

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Chemical Property of Acetic acid (2R,4aR,6S,8S,8aS)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester

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Technology Process of Acetic acid (2R,4aR,6S,8S,8aS)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester

There total 5 articles about Acetic acid (2R,4aR,6S,8S,8aS)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 3-Trifluoromethyl-benzoic acid (2R,4aR,6S,7R,8S,8aR)-8-acetoxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester

: 6838-11-5,52443-47-7,66512-94-5,84622-62-8,113473-38-4
methyl 2-deoxy-3-O-acetyl-4,6-O-benzylidene-α-D-glucopyranoside

Guidance literature:: With magnesium(II) perchlorate; 9-ethyl-3,6-dimethyl-9H-carbazole; In water; isopropyl alcohol; at 23 ℃; for 2h; Irradiation;
DOI:10.1021/jo971332y

Reference yield: 84.0%

: 198837-07-9
methyl-[O³-acetyl-O²-benzoyl-O⁴,O⁶-((R)-benzylidene)-α-D-glucopyranoside]

: 6838-11-5,52443-47-7,66512-94-5,84622-62-8,113473-38-4
methyl 2-deoxy-3-O-acetyl-4,6-O-benzylidene-α-D-glucopyranoside

Guidance literature:: With magnesium(II) perchlorate; 9-ethyl-3,6-dimethyl-9H-carbazole; In water; isopropyl alcohol; at 23 ℃; for 2h; Irradiation;
DOI:10.1021/jo971332y

Reference yield:

: 3162-96-7
4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside

: 6838-11-5,52443-47-7,66512-94-5,84622-62-8,113473-38-4
methyl 2-deoxy-3-O-acetyl-4,6-O-benzylidene-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) Bu₂SnO, 2.) Bu₄NF / 1.) toluene, 2.) THF, CH₂Cl₂

2: 85 percent / magnesium perchlorate hydrate, 3,6-dimethyl-9-ethylcarbazole / H₂O; propan-2-ol / 2 h / 23 °C / Irradiation

With magnesium(II) perchlorate; 9-ethyl-3,6-dimethyl-9H-carbazole; tetrabutyl ammonium fluoride; di(n-butyl)tin oxide; In water; isopropyl alcohol;
DOI:10.1021/jo971332y