(1S,2R,3R,4S,5S,6R)-3,4-Bis-benzyloxy-5,6-bis-(4-methoxy-benzyloxy)-cyclohexane-1,2-diol

Base Information

Chemical Name:(1S,2R,3R,4S,5S,6R)-3,4-Bis-benzyloxy-5,6-bis-(4-methoxy-benzyloxy)-cyclohexane-1,2-diol
CAS No.:155154-67-9
Molecular Formula:C₃₆H₄₀O₈
Molecular Weight:600.709
Hs Code.:

Synonyms:(1S,2R,3R,4S,5S,6R)-3,4-Bis-benzyloxy-5,6-bis-(4-methoxy-benzyloxy)-cyclohexane-1,2-diol

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Chemical Property of (1S,2R,3R,4S,5S,6R)-3,4-Bis-benzyloxy-5,6-bis-(4-methoxy-benzyloxy)-cyclohexane-1,2-diol

Chemical Property:

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Technology Process of (1S,2R,3R,4S,5S,6R)-3,4-Bis-benzyloxy-5,6-bis-(4-methoxy-benzyloxy)-cyclohexane-1,2-diol

There total 6 articles about (1S,2R,3R,4S,5S,6R)-3,4-Bis-benzyloxy-5,6-bis-(4-methoxy-benzyloxy)-cyclohexane-1,2-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: (S)-Acetoxy-phenyl-acetic acid (1S,2S,3R,4S,5R,6S)-3,4-bis-benzyloxy-2-hydroxy-5,6-bis-(4-methoxy-benzyloxy)-cyclohexyl ester

: 155154-67-9
(1S,2R,3R,4S,5S,6R)-3,4-Bis-benzyloxy-5,6-bis-(4-methoxy-benzyloxy)-cyclohexane-1,2-diol

Guidance literature:: With sodium methylate; In methanol; at 0 ℃;
DOI:10.1039/c39940000111

Reference yield:

: 6763-49-1,23393-19-3,33021-17-9,34361-61-0,34395-04-5,34711-26-7,40773-57-7,41545-19-1,54712-58-2,57089-24-4,57089-25-5,68738-25-0,81601-23-2,120710-65-8,141506-87-8
(+/-)-1,2:5,6-dicyclohexylidene-myo-inositol

: 155154-67-9
(1S,2R,3R,4S,5S,6R)-3,4-Bis-benzyloxy-5,6-bis-(4-methoxy-benzyloxy)-cyclohexane-1,2-diol

Guidance literature:: Multi-step reaction with 6 steps

1: NaH / dimethylformamide

2: TsOH, EtOH / Ambient temperature

3: NaH / dimethylformamide

4: aq. AcOH / 80 °C

5: 31 percent / dicyclohexylcarbodiimide, 4-dimethylaminopyridine / CH₂Cl₂ / -15 °C

6: 100 percent / NaOMe / methanol / 0 °C

With dmap; ethanol; sodium methylate; sodium hydride; toluene-4-sulfonic acid; acetic acid; dicyclohexyl-carbodiimide; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1039/c39940000111

Reference yield:

: 13035-66-0,116180-54-2,126722-41-6
(+/-)-3,4-di-O-benzyl-1,2-cyclohexylidene-myo-inositol

: 155154-67-9
(1S,2R,3R,4S,5S,6R)-3,4-Bis-benzyloxy-5,6-bis-(4-methoxy-benzyloxy)-cyclohexane-1,2-diol

Guidance literature:: Multi-step reaction with 4 steps

1: NaH / dimethylformamide

2: aq. AcOH / 80 °C

3: 31 percent / dicyclohexylcarbodiimide, 4-dimethylaminopyridine / CH₂Cl₂ / -15 °C

4: 100 percent / NaOMe / methanol / 0 °C

With dmap; sodium methylate; sodium hydride; acetic acid; dicyclohexyl-carbodiimide; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1039/c39940000111