cis-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane

Base Information

• Chemical Name: cis-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane
• CAS No.: 114789-83-2
• Molecular Formula: C₃₅H₂₈O
• Molecular Weight: 464.607
• Mol file: 114789-83-2.mol

Synonyms:cis-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane

Chemical Property of cis-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane

There total 8 articles about cis-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.0%

1,2,2,5,5-pentaphenyl-4-penten-1-one (57365-26-1) → 1,1,4,4-tetraphenyl-1,3-butadiene (1450-63-1) + cis-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane (114789-83-2) + trans-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane (114789-84-3)

Guidance literature:

In acetonitrile; at 94 ℃; for 1.56667h; Irradiation;

DOI:10.1021/jo00251a024

Reference yield: 17.9%

1,1,3,5,5-pentaphenyl-1,4-pentadien-3-ol (114789-76-3) → 1,1,4,4-tetraphenyl-1,3-butadiene (1450-63-1) + cis-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane (114789-83-2) + trans-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane (114789-84-3)

Guidance literature:

With 4-(Dimethylamino)benzophenone; In acetonitrile; for 0.666667h; Irradiation;

DOI:10.1021/jo00251a024

Reference yield: 14.4%

1,1,3,5,5-pentaphenyl-1,4-pentadien-3-ol (114789-76-3) → 1,1,4,4-tetraphenyl-1,3-butadiene (1450-63-1) + 1,2,2,5,5-pentaphenyl-4-penten-1-one (57365-26-1) + cis-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane (114789-83-2) + trans-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane (114789-84-3)

Guidance literature:

In acetonitrile; for 5.2h; Irradiation;

DOI:10.1021/jo00251a024

upstream raw materials:

1,2,2,5,5-pentaphenyl-4-penten-1-one

1,1,3,5,5-pentaphenyl-1,4-pentadien-3-ol

1,2,2-triphenylethan-1-one

3-bromo-1,1-diphenyl-1-propene

Downstream raw materials:

1,2,2,5,5-pentaphenyl-4-penten-1-one

1,4,4-triphenyl-2-(1,1-diphenylmethyl)-3-buten-1-one

1,1,4,4-tetraphenyl-1,3-butadiene

trans-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane

Refernces