cis-dihydrido(trifluorophosphine)tris(triphenylphosphine)osmium(II)

Base Information

• Chemical Name: cis-dihydrido(trifluorophosphine)tris(triphenylphosphine)osmium(II)
• CAS No.: 68448-20-4
• Molecular Formula: C₅₄H₄₇F₃OsP₄
• Molecular Weight: 1067.06
• Mol file: 68448-20-4.mol

Synonyms:cis-dihydrido(trifluorophosphine)tris(triphenylphosphine)osmium(II)

Chemical Property of cis-dihydrido(trifluorophosphine)tris(triphenylphosphine)osmium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-dihydrido(trifluorophosphine)tris(triphenylphosphine)osmium(II)

There total 2 articles about cis-dihydrido(trifluorophosphine)tris(triphenylphosphine)osmium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

tetrahydridotris(triphenylphosphine)osmium(IV) (24228-59-9) → cis-dihydrido(trifluorophosphine)tris(triphenylphosphine)osmium(II) (68448-20-4)

Guidance literature:

With trifluorophosphane; In not given; sealed vessel (vac.); shaking of Os-complex with excess of PF3 (60°C, 16 h); solvent removal, washing (hexane), recrystn. (CH2Cl2/hexane); elem. anal.;

DOI:10.1039/DT9780000885

Reference yield:

tetrahydridotris(triphenylphosphine)osmium(IV) (24228-59-9) + trifluorophosphane (7783-55-3) → cis-dihydrido(trifluorophosphine)tris(triphenylphosphine)osmium(II) (68448-20-4)

Guidance literature:

In benzene;

DOI:10.1039/DT9780000885

Reference yield: 97.0%

cis-dihydrido(trifluorophosphine)tris(triphenylphosphine)osmium(II) (68448-20-4) → cis-chlorohydridobis(trifluorophosphine)bis(triphenylphosphine)osmium(II) (68448-22-6)

Guidance literature:

With HCl; In benzene; 2 equiv. HCl (sealed vessel, vac., 75°C, 12 h); elem. anal.;

DOI:10.1039/DT9780000889

upstream raw materials:

tetrahydridotris(triphenylphosphine)osmium(IV)

trifluorophosphane

Downstream raw materials:

cis-chlorohydridobis(trifluorophosphine)bis(triphenylphosphine)osmium(II)

cis-[OsH₂(trifluorophosphine)2(triphenylphosphine)2]