{PtH2(μ-H)(μ-dppm)2}PF6

Base Information

• Chemical Name: {PtH2(μ-H)(μ-dppm)2}PF6
• CAS No.: 63911-00-2
• Molecular Formula: C₅₀H₄₇P₄Pt₂*F₆P
• Molecular Weight: 1306.94
• Mol file: 63911-00-2.mol

Synonyms:{PtH2(μ-H)(μ-dppm)2}PF6

Chemical Property of {PtH2(μ-H)(μ-dppm)2}PF6

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {PtH2(μ-H)(μ-dppm)2}PF6

There total 7 articles about {PtH2(μ-H)(μ-dppm)2}PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

[Pt2H(CO)(μ-bis(diphenylphosphino)methane)2]PF6 (74587-82-9) → {PtH2(μ-H)(μ-dppm)2}PF6 (63911-00-2)

Guidance literature:

With H₂; In dichloromethane; byproducts: CO; H2 passed through Pt complex for 10 min, CH2Cl2 injected into reaction flask, reaction allowed to proceed for 72 h at room temp., the flask flushed with H2 at 24-h intervals; partial evapn. in a stream of N2, addn. of MeOH;

Reference yield: 50.0%

ammonium hexafluorophosphate + [Pt2H2(H)(((C6H5)2P)2CH2)2](1+)*Cl(1-)=[Pt2H2(H)(((C6H5)2P)2CH2)2]Cl (63910-98-5) → {PtH2(μ-H)(μ-dppm)2}PF6 (63911-00-2)

Guidance literature:

In methanol; recrystn. from MeOH soln. of NH4PF6;

Reference yield:

[Pt2H(CH3CN)(bis(diphenylphosphino)methane)2]PF6 (79680-18-5) → {PtH2(μ-H)(μ-dppm)2}PF6 (63911-00-2)

Guidance literature:

With hydrogen; 25°C, 1 atm;

DOI:10.1021/ja00414a050

upstream raw materials:

[Pt₂H₂(H)(((C₆H₅)2P)2CH₂)2]⁽¹⁺⁾*Cl^(1-)=[Pt₂H₂(H)(((C₆H₅)2P)2CH₂)2]Cl

[Pt₂H(CH₃CN)(bis(diphenylphosphino)methane)2]PF₆

[Pt2H(CO)(μ-bis(diphenylphosphino)methane)2]PF6

[Pt2(CO)2(μ-dppm)2]PF6

Downstream raw materials:

hydrogen

bis-μ-[bis(diphenylphosphino)methane]-bis(chloroplatinum)(Pt-Pt)

Pt₂((C₆H₅)4P₂CH₂)2HP(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)

[Pt2H(CO)(μ-bis(diphenylphosphino)methane)2]PF6