2-(benzo[1,3]dioxol-5-yl-triisopropylsilanyloxy-methyl)-acrylic acid methyl ester

Base Information

Chemical Name:2-(benzo[1,3]dioxol-5-yl-triisopropylsilanyloxy-methyl)-acrylic acid methyl ester
CAS No.:445417-95-8
Molecular Formula:C₂₁H₃₂O₅Si
Molecular Weight:392.568
Hs Code.:

Synonyms:2-(benzo[1,3]dioxol-5-yl-triisopropylsilanyloxy-methyl)-acrylic acid methyl ester

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Chemical Property of 2-(benzo[1,3]dioxol-5-yl-triisopropylsilanyloxy-methyl)-acrylic acid methyl ester

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Technology Process of 2-(benzo[1,3]dioxol-5-yl-triisopropylsilanyloxy-methyl)-acrylic acid methyl ester

There total 1 articles about 2-(benzo[1,3]dioxol-5-yl-triisopropylsilanyloxy-methyl)-acrylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 218934-11-3
methyl 3-hydroxy-2-methylene-3-[(3,4-methylenedioxy)phenyl]propanoate

: 445417-95-8
2-(benzo[1,3]dioxol-5-yl-triisopropylsilanyloxy-methyl)-acrylic acid methyl ester

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 20 ℃; for 0.5h;
DOI:10.1016/S0040-4039(02)00351-9

Reference yield:

: 445417-95-8
2-(benzo[1,3]dioxol-5-yl-triisopropylsilanyloxy-methyl)-acrylic acid methyl ester

: 445417-90-3
5-[2-(tert-butyl-diphenyl-silanyloxymethyl)-1-triisopropylsilanyloxy-allyl]-benzo[1,3]dioxole

Guidance literature:: Multi-step reaction with 2 steps

1: DIBAL-H / CH₂Cl₂ / 2 h / -78 °C

2: 90 percent / imidazole / dimethylformamide / 14 h / 20 °C

With 1H-imidazole; diisobutylaluminium hydride; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(03)01307-8

Reference yield:

: 445417-95-8
2-(benzo[1,3]dioxol-5-yl-triisopropylsilanyloxy-methyl)-acrylic acid methyl ester

: (2S,3R)-3-Benzo[1,3]dioxol-5-yl-2-(tert-butyl-diphenyl-silanyloxymethyl)-3-triisopropylsilanyloxy-propionic acid

Guidance literature:: Multi-step reaction with 5 steps

1.1: DIBAL-H / CH₂Cl₂ / 2 h / -78 °C

2.1: 90 percent / imidazole / dimethylformamide / 14 h / 20 °C

3.1: 9-BBN / tetrahydrofuran / 0 - 20 °C

3.2: NaOH; H₂O₂ / 1.5 h / 0 - 20 °C

4.1: TPAP; NMO; 4 Angstroem MS / CH₂Cl₂ / 1 h / 20 °C

5.1: sodium chlorite; NaHPO₄ / 2-methyl-propan-2-ol; isobutylene / 4 h / 0 - 20 °C

With 1H-imidazole; sodium chlorite; 9-borabicyclo[3.3.1]nonane dimer; N-methyl-2-indolinone; tetrapropylammonium perruthennate; 4 Angstroem MS; camphor-10-sulfonic acid; diisobutylaluminium hydride; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; isobutene; tert-butyl alcohol;
DOI:10.1016/S0040-4039(03)01307-8