[6-Methoxy-8-(methylsulfanylcarbothioylamino)-2-phenyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-7-yl] methanesulfonate

Base Information

Chemical Name:[6-Methoxy-8-(methylsulfanylcarbothioylamino)-2-phenyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-7-yl] methanesulfonate
CAS No.:6945-62-6
Molecular Formula:C17H23 N O7 S3
Molecular Weight:0
Hs Code.:
DSSTox Substance ID:DTXSID30405387
NSC Number:52400
Mol file:6945-62-6.mol

Synonyms:6945-62-6;NSC52400;DTXSID30405387;NSC-52400;AG-G-70351

Suppliers and Price of [6-Methoxy-8-(methylsulfanylcarbothioylamino)-2-phenyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-7-yl] methanesulfonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of [6-Methoxy-8-(methylsulfanylcarbothioylamino)-2-phenyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-7-yl] methanesulfonate

Chemical Property:

Vapor Pressure:1.82E-15mmHg at 25°C
Refractive Index:1.619
Boiling Point:623.5°C at 760 mmHg
Flash Point:330.9°C
PSA：158.09000
Density:1.43g/cm³
LogP:2.89450
XLogP3:1.5
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:9
Rotatable Bond Count:6
Exact Mass:449.06366559
Heavy Atom Count:28
Complexity:635

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1C(C(C2C(O1)COC(O2)C3=CC=CC=C3)NC(=S)SC)OS(=O)(=O)C

Technology Process of [6-Methoxy-8-(methylsulfanylcarbothioylamino)-2-phenyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-7-yl] methanesulfonate

There total 1 articles about [6-Methoxy-8-(methylsulfanylcarbothioylamino)-2-phenyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-7-yl] methanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 6945-62-6
methyl O⁴,O⁶-(R)-benzylidene-O²-methanesulfonyl-3-methylsulfanylthiocarbonylamino-α-D-3-deoxy-altropyranoside

Guidance literature:: Methansulfonylchlorid in Lsg. v. Methyl-4,6-O-benzyliden-3-deoxy-3-(dithiocarbomethoxy)-amino-α-D-altropyranosid in Py. eintropfen, 0grad, 24 Std.;

Reference yield:

: 6945-62-6
methyl O⁴,O⁶-(R)-benzylidene-O²-methanesulfonyl-3-methylsulfanylthiocarbonylamino-α-D-3-deoxy-altropyranoside

: 7147-13-9
methyl O⁴,O⁶-(R)-benzylidene-2,3-methylsulfanylthiocarbonylazanediyl-α-D-2,3-dideoxy-allopyranoside

Guidance literature:: With sodium methylate; In methanol; 2-methoxy-ethanol;
DOI:10.1021/ja01502a070

Reference yield:

: 6945-62-6
methyl O⁴,O⁶-(R)-benzylidene-O²-methanesulfonyl-3-methylsulfanylthiocarbonylamino-α-D-3-deoxy-altropyranoside

: 6945-10-4
(4aR)-6c-methoxy-2ξ-phenyl-(4ar,6at,9at,9bt)-octahydro-[1,3]dioxino[4',5':5,6]pyrano[4,3-d]thiazole

Guidance literature:: Multi-step reaction with 2 steps

1: Py / Heating

2: Al-Hg, H₂O / tetrahydrofuran

With pyridine; aluminium amalgam; water; In tetrahydrofuran;