2-(Bicyclo(2.2.1)hept-2-ylidenemethyl)-1-methyl-5-nitro-1H-imidazole

Base Information

Chemical Name:2-(Bicyclo(2.2.1)hept-2-ylidenemethyl)-1-methyl-5-nitro-1H-imidazole
CAS No.:97945-32-9
Molecular Formula:C₁₂H₁₅N₃O₂
Molecular Weight:233.27
Hs Code.:
Nikkaji Number:J389.475D

Synonyms:2-(Bicyclo(2.2.1)hept-2-ylidenemethyl)-1-methyl-5-nitro-1H-imidazole;1H-Imidazole, 2-(bicyclo(2.2.1)hept-2-ylidenemethyl)-1-methyl-5-nitro-;97945-32-9;C12H16N3O2;C12-H16-N3-O2;LS-78072;1-Methyl-2-[(norbornan-2-ylidene)methyl]-5-nitro-1H-imidazole

Suppliers and Price of 2-(Bicyclo(2.2.1)hept-2-ylidenemethyl)-1-methyl-5-nitro-1H-imidazole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 2-(Bicyclo(2.2.1)hept-2-ylidenemethyl)-1-methyl-5-nitro-1H-imidazole

Chemical Property:

Vapor Pressure:9.78E-08mmHg at 25°C
Refractive Index:1.5290 (estimate)
Boiling Point:434°C at 760 mmHg
Flash Point:216.3°C
PSA：63.64000
Density:1.45g/cm³
LogP:3.05490
XLogP3:1.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:233.116426730
Heavy Atom Count:17
Complexity:363

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CN1C(=CN=C1C=C2CC3CCC2C3)[N+](=O)[O-]
Isomeric SMILES:CN1C(=CN=C1/C=C/2\CC3CCC2C3)[N+](=O)[O-]

Technology Process of 2-(Bicyclo(2.2.1)hept-2-ylidenemethyl)-1-methyl-5-nitro-1H-imidazole

There total 6 articles about 2-(Bicyclo(2.2.1)hept-2-ylidenemethyl)-1-methyl-5-nitro-1H-imidazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 97945-37-4
1-methyl 2-(2-nitronorbornan-2-ylmethyl) 5-nitroimidazole

: 97945-32-9
(E)-1-methyl 2-(2-norbornanylidenemethyl) 5-nitroimidazole

Guidance literature:: With tetra(n-butyl)ammonium hydroxide; In benzene; for 4h; Heating; Irradiation;
DOI:10.1016/0223-5234(91)90026-J

Reference yield: 94.0%

: 97945-37-4
1-Methyl-5-nitro-2-(2-nitro-bicyclo[2.2.1]hept-2-ylmethyl)-1H-imidazole

: 97945-32-9
2-Bicyclo[2.2.1]hept-(2Z)-ylidenemethyl-1-methyl-5-nitro-1H-imidazole

Guidance literature:: With tetra(n-butyl)ammonium hydroxide; In benzene; for 4h; Heating;
DOI:10.1016/S0040-4039(00)98502-2

Reference yield:

: 7242-92-4
exo-2-aminonorbornane

: 97945-32-9
(E)-1-methyl 2-(2-norbornanylidenemethyl) 5-nitroimidazole

Guidance literature:: Multi-step reaction with 3 steps

1: 73 percent / 85percent m-chloroperbenzoic acid / 1,2-dichloro-ethane / 3 h / 83 °C

2: 1.) 40percent aq. (n-Bu)4NOH / 1.) 1 h, 2.) CH2Cl2, hν, RT, 12 h

3: 94 percent / 40percent aq. (n-Bu)4NOH / benzene / 4 h / Heating; Irradiation

With tetra(n-butyl)ammonium hydroxide; 3-chloro-benzenecarboperoxoic acid; In 1,2-dichloro-ethane; benzene;
DOI:10.1016/0223-5234(91)90026-J