tris-[2,6-dimethyl-4-(N-tert-butyl-N-hydroxyamino)phenyl]borane

Base Information

Chemical Name:tris-[2,6-dimethyl-4-(N-tert-butyl-N-hydroxyamino)phenyl]borane
CAS No.:263844-34-4
Molecular Formula:C₃₆H₅₄BN₃O₃
Molecular Weight:587.654
Hs Code.:

Synonyms:tris-[2,6-dimethyl-4-(N-tert-butyl-N-hydroxyamino)phenyl]borane

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Chemical Property of tris-[2,6-dimethyl-4-(N-tert-butyl-N-hydroxyamino)phenyl]borane

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Technology Process of tris-[2,6-dimethyl-4-(N-tert-butyl-N-hydroxyamino)phenyl]borane

There total 2 articles about tris-[2,6-dimethyl-4-(N-tert-butyl-N-hydroxyamino)phenyl]borane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 263844-33-3
tris-[2,6-dimethyl-4-(O-tert-butyldimethylsilyl-N-tert-butyl-N-hydroxyamino)phenyl]borane

: 263844-34-4
tris-[2,6-dimethyl-4-(N-tert-butyl-N-hydroxyamino)phenyl]borane

Guidance literature:: With acetic acid; In tetrahydrofuran; a mixt. of glacial acetic acid and borane in THF was stirred at room temp. for 30 min under Ar; diluted with H2O, ppt. was washed with water;
DOI:10.1021/ja9920819

Reference yield:

: 263844-32-2
N-(4-bromo-3,5-dimethylphenyl)-O-tert-butyldimethylsilyl-N-tert-butylhydroxyamine

: 263844-34-4
tris-[2,6-dimethyl-4-(N-tert-butyl-N-hydroxyamino)phenyl]borane

Guidance literature:: Multi-step reaction with 2 steps

1: n-butyllithium / diethyl ether

2: acetic acid / tetrahydrofuran

With n-butyllithium; acetic acid; In tetrahydrofuran; diethyl ether;
DOI:10.1021/ja9920819

Reference yield: 98.0%

: 263844-34-4
tris-[2,6-dimethyl-4-(N-tert-butyl-N-hydroxyamino)phenyl]borane

: tris-[2,6-dimethyl-4-(N-tert-butyl-N-oxyamino)phenyl]borane

Guidance literature:: With Ag₂O; In dichloromethane; to a soln. of borane in CH2Cl2 was added an excess of freshly prepared Ag2O and the mixt. was stirred for 30 min (N2 atm.); filtered, the solvent was removed, chromd. on Al2O3 with CH2Cl2; elem. anal.;
DOI:10.1021/ja9920819