4-{Methyl-[(2E,4E)-3-methyl-5-(2,6,6-trimethyl-cyclohex-1-enyl)-penta-2,4-dienoyl]-amino}-benzoic acid 2-trimethylsilanyl-ethyl ester

Base Information

Chemical Name:4-{Methyl-[(2E,4E)-3-methyl-5-(2,6,6-trimethyl-cyclohex-1-enyl)-penta-2,4-dienoyl]-amino}-benzoic acid 2-trimethylsilanyl-ethyl ester
CAS No.:212118-27-9
Molecular Formula:C₂₈H₄₁NO₃Si
Molecular Weight:467.724
Hs Code.:

Synonyms:4-{Methyl-[(2E,4E)-3-methyl-5-(2,6,6-trimethyl-cyclohex-1-enyl)-penta-2,4-dienoyl]-amino}-benzoic acid 2-trimethylsilanyl-ethyl ester

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Chemical Property of 4-{Methyl-[(2E,4E)-3-methyl-5-(2,6,6-trimethyl-cyclohex-1-enyl)-penta-2,4-dienoyl]-amino}-benzoic acid 2-trimethylsilanyl-ethyl ester

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Technology Process of 4-{Methyl-[(2E,4E)-3-methyl-5-(2,6,6-trimethyl-cyclohex-1-enyl)-penta-2,4-dienoyl]-amino}-benzoic acid 2-trimethylsilanyl-ethyl ester

There total 8 articles about 4-{Methyl-[(2E,4E)-3-methyl-5-(2,6,6-trimethyl-cyclohex-1-enyl)-penta-2,4-dienoyl]-amino}-benzoic acid 2-trimethylsilanyl-ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 79-77-6,14901-07-6
(E)-β-ionone

: 212118-27-9
4-{Methyl-[(2E,4E)-3-methyl-5-(2,6,6-trimethyl-cyclohex-1-enyl)-penta-2,4-dienoyl]-amino}-benzoic acid 2-trimethylsilanyl-ethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 90 percent / MeOH / benzene / 9 h / 40 °C

2: 37 percent / aq. KOH / tetrahydrofuran; methanol / 12 h / Ambient temperature

3: hexachloroacetone, Ph₃P / 0.5 h / 10 °C

4: pyridine / 0.33 h / 0 °C

With pyridine; methanol; potassium hydroxide; 1,1,1,3,3,3-hexachloro-propan-2-one; triphenylphosphine; In tetrahydrofuran; methanol; benzene;
DOI:10.1021/jm9801354

Reference yield:

: 10541-83-0,937737-33-2
N-methyl-p-aminobenzoic acid

: 212118-27-9
4-{Methyl-[(2E,4E)-3-methyl-5-(2,6,6-trimethyl-cyclohex-1-enyl)-penta-2,4-dienoyl]-amino}-benzoic acid 2-trimethylsilanyl-ethyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: trifluoroacetic anhydride / 0 °C

2: CCl₄, Ph₃P / acetonitrile / 0.33 h

3: acetonitrile / 0.25 h / Heating

4: aq. 1percent Na₂CO₃ / tetrahydrofuran; methanol / Ambient temperature

5: pyridine / 0.33 h / 0 °C

With pyridine; tetrachloromethane; sodium carbonate; triphenylphosphine; trifluoroacetic anhydride; In tetrahydrofuran; methanol; acetonitrile;
DOI:10.1021/jm9801354

Reference yield:

: 5300-00-5
(2E,4E)-3-Methyl-5-(2,6,6-trimethyl-cyclohex-1-enyl)-penta-2,4-dienoic acid methyl ester

: 212118-27-9
4-{Methyl-[(2E,4E)-3-methyl-5-(2,6,6-trimethyl-cyclohex-1-enyl)-penta-2,4-dienoyl]-amino}-benzoic acid 2-trimethylsilanyl-ethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 37 percent / aq. KOH / tetrahydrofuran; methanol / 12 h / Ambient temperature

2: hexachloroacetone, Ph₃P / 0.5 h / 10 °C

3: pyridine / 0.33 h / 0 °C

With pyridine; potassium hydroxide; 1,1,1,3,3,3-hexachloro-propan-2-one; triphenylphosphine; In tetrahydrofuran; methanol;
DOI:10.1021/jm9801354