4-(2,3-dihydro-1H-naphtho[1,8-de]-1,3,2-diazaborinyl)-6',6''-dimethoxy-4'''-methyl-1,1':3',1'':3'',1'''-quaterphenyl

Base Information

Chemical Name:4-(2,3-dihydro-1H-naphtho[1,8-de]-1,3,2-diazaborinyl)-6',6''-dimethoxy-4'''-methyl-1,1':3',1'':3'',1'''-quaterphenyl
CAS No.:927384-60-9
Molecular Formula:C₃₇H₃₁BN₂O₂
Molecular Weight:546.476
Hs Code.:

Synonyms:4-(2,3-dihydro-1H-naphtho[1,8-de]-1,3,2-diazaborinyl)-6',6''-dimethoxy-4'''-methyl-1,1':3',1'':3'',1'''-quaterphenyl

Suppliers and Price of 4-(2,3-dihydro-1H-naphtho[1,8-de]-1,3,2-diazaborinyl)-6',6''-dimethoxy-4'''-methyl-1,1':3',1'':3'',1'''-quaterphenyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4-(2,3-dihydro-1H-naphtho[1,8-de]-1,3,2-diazaborinyl)-6',6''-dimethoxy-4'''-methyl-1,1':3',1'':3'',1'''-quaterphenyl

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 4-(2,3-dihydro-1H-naphtho[1,8-de]-1,3,2-diazaborinyl)-6',6''-dimethoxy-4'''-methyl-1,1':3',1'':3'',1'''-quaterphenyl

There total 8 articles about 4-(2,3-dihydro-1H-naphtho[1,8-de]-1,3,2-diazaborinyl)-6',6''-dimethoxy-4'''-methyl-1,1':3',1'':3'',1'''-quaterphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 927384-44-9
2-(4-bromophenyl)-2,3-dihydro-1H-naphtho[1,8-de] [1,3,2]diazaborinine

: 927384-56-3
3-(2,3-dihydro-1H-naphtho[1,8-de]-1,3,2-diazaborinyl)-4,6'-dimethoxy-4''-methyl-1,1':3',1''-terphenyl

: 927384-60-9
4-(2,3-dihydro-1H-naphtho[1,8-de]-1,3,2-diazaborinyl)-6',6''-dimethoxy-4'''-methyl-1,1':3',1'':3'',1'''-quaterphenyl

Guidance literature:: With water; cesium fluoride; bis(tri-t-butylphosphine)palladium⁽⁰⁾; In tetrahydrofuran; water; B compd. reacted with aq. acid in THF at room temp., reacted with Pd complex and CsF in THF at 60°C;
DOI:10.1021/ja067975p

Reference yield:

: 927384-44-9
2-(4-bromophenyl)-2,3-dihydro-1H-naphtho[1,8-de] [1,3,2]diazaborinine

: 927384-57-4
C₂₁H₂₁BO₄

: 927384-60-9
4-(2,3-dihydro-1H-naphtho[1,8-de]-1,3,2-diazaborinyl)-6',6''-dimethoxy-4'''-methyl-1,1':3',1'':3'',1'''-quaterphenyl

Guidance literature:: With cesium fluoride; bis(tri-t-butylphosphine)palladium⁽⁰⁾; In tetrahydrofuran; at 60 ℃; for 24h;
DOI:10.1021/ja067975p

Reference yield:

: 927384-45-0
4-bromo-2-(2,3-dihydro-1H-naphtho[1,8-de]-1,3,2-diazaborinyl)-1-methoxybenzene

: 927384-60-9
4-(2,3-dihydro-1H-naphtho[1,8-de]-1,3,2-diazaborinyl)-6',6''-dimethoxy-4'''-methyl-1,1':3',1'':3'',1'''-quaterphenyl

Guidance literature:: Multi-step reaction with 3 steps

1: 1.55 g / CsF / Pd[P(t-Bu)3]2 / tetrahydrofuran / 9 h / 60 °C

2: aq. H₂SO₄ / tetrahydrofuran / 14 h / 20 °C

3: 2.04 g / CsF / Pd[P(t-Bu)3]2 / tetrahydrofuran / 24 h / 60 °C

With sulfuric acid; cesium fluoride; bis(tri-t-butylphosphine)palladium⁽⁰⁾; In tetrahydrofuran; 1: Suzuki-Miyaura reaction / 3: Suzuki-Miyaura reaction;
DOI:10.1021/ja067975p