(5r)-5-Hydroxy-4-{2-[(2r,4ar,8ar)-1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-yl]ethyl}furan-2(5h)-one

Base Information

Chemical Name:(5r)-5-Hydroxy-4-{2-[(2r,4ar,8ar)-1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-yl]ethyl}furan-2(5h)-one
CAS No.:92593-91-4
Molecular Formula:C₂₀H₃₀O₃
Molecular Weight:318.456
Hs Code.:
DSSTox Substance ID:DTXSID10276279
Mol file:92593-91-4.mol

Synonyms:16-HCDO;16-hydroxycleroda-3,13(14)-dien-15,16-olide

Suppliers and Price of (5r)-5-Hydroxy-4-{2-[(2r,4ar,8ar)-1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-yl]ethyl}furan-2(5h)-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of (5r)-5-Hydroxy-4-{2-[(2r,4ar,8ar)-1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-yl]ethyl}furan-2(5h)-one

Chemical Property:

Vapor Pressure:1.26E-10mmHg at 25°C
Boiling Point:465.6°Cat760mmHg
Flash Point:186.3°C
Density:1.057g/cm³
XLogP3:4.5
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:318.21949481
Heavy Atom Count:23
Complexity:561

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1CCC2(C(C1(C)CCC3=CC(=O)OC3O)CCC=C2C)C
Isomeric SMILES:C[C@@H]1CC[C@@]2([C@@H](C1(C)CCC3=CC(=O)O[C@H]3O)CCC=C2C)C

Technology Process of (5r)-5-Hydroxy-4-{2-[(2r,4ar,8ar)-1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-yl]ethyl}furan-2(5h)-one

There total 41 articles about (5r)-5-Hydroxy-4-{2-[(2r,4ar,8ar)-1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-yl]ethyl}furan-2(5h)-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 213020-08-7
(4aα,6β,8aβ)-5(R)-[2-(3-furanyl)ethyl]-1,5,6,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalene

: 141979-19-3,92593-91-4
(4aα,6β,8aβ)-5(R)-[2-(2,5-dihydro-5-hydroxy-2-oxo-4-furanyl)ethyl]-1,5,6,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalene

Guidance literature:: With oxygen; rose bengal; diisopropylamine; In dichloromethane; at -78 ℃; for 6h; Irradiation;
DOI:10.1021/np000105f

Reference yield: 70.0%

: 41943-73-1,55732-74-6,106189-95-1,106190-10-7,106190-14-1
(±)-(4-(1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-yl)ethyl)furan-2(5H)-one

: 141979-19-3,92593-91-4
(±)-16-hydroxycleroda-3,13 (14)Z-dien-15,16-olide

Guidance literature:: (±)-(4-(1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-yl)ethyl)furan-2(5H)-one; With t-butyldimethylsiyl triflate; triethylamine; In dichloromethane; at 20 ℃; for 0.55h; Inert atmosphere;

With 2-methyl-but-2-ene; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃; for 0.5h; Inert atmosphere;

In acetone; at 20 ℃; for 0.25h; Inert atmosphere;
DOI:10.1021/ja512527s