(4aR,6S,7S,8S,8aS)-7-amino-6-methoxy-2-phenyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-8-ol

Base Information

Chemical Name:(4aR,6S,7S,8S,8aS)-7-amino-6-methoxy-2-phenyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-8-ol
CAS No.:6038-60-4
Molecular Formula:C14H19NO5
Molecular Weight:281.309
Hs Code.:
Nikkaji Number:J81.134C
Mol file:6038-60-4.mol

Synonyms:SCHEMBL7153770

Suppliers and Price of (4aR,6S,7S,8S,8aS)-7-amino-6-methoxy-2-phenyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-8-ol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
3-AMINO-4-METHOXY-9-PHENYL-5,8,10-TRIOXABICYCLO[4.4.0]DECAN-2-OL 95.00%
10G
$ 1334.03

American Custom Chemicals Corporation
3-AMINO-4-METHOXY-9-PHENYL-5,8,10-TRIOXABICYCLO[4.4.0]DECAN-2-OL 95.00%
5G
$ 909.56

Total 8 raw suppliers

Chemical Property of (4aR,6S,7S,8S,8aS)-7-amino-6-methoxy-2-phenyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-8-ol

Chemical Property:

Vapor Pressure:1.8E-09mmHg at 25°C
Boiling Point:465.7°C at 760 mmHg
Flash Point:235.4°C
PSA：83.17000
Density:1.31g/cm³
LogP:0.86040
XLogP3:-0.4
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:2
Exact Mass:281.12632271
Heavy Atom Count:20
Complexity:323

Purity/Quality:

97% ^*data from raw suppliers

3-AMINO-4-METHOXY-9-PHENYL-5,8,10-TRIOXABICYCLO[4.4.0]DECAN-2-OL 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1C(C(C2C(O1)COC(O2)C3=CC=CC=C3)O)N
Isomeric SMILES:CO[C@@H]1[C@H]([C@@H]([C@H]2[C@H](O1)COC(O2)C3=CC=CC=C3)O)N

Technology Process of (4aR,6S,7S,8S,8aS)-7-amino-6-methoxy-2-phenyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-8-ol

There total 4 articles about (4aR,6S,7S,8S,8aS)-7-amino-6-methoxy-2-phenyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-8-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 17460-37-6
methyl 2-azido-4,6-O-benzylidene-2-deoxy-α-D-altropyranoside

: 6038-60-4
methyl 2-amino-4,6-O-benzylidene-2-deoxy-α-D-altropyranoside

Guidance literature:: With (Sn(SPh)3)(Et₃N); In benzene; at 15 ℃; for 0.0833333h;
DOI:10.1016/S0040-4039(01)81096-0

Reference yield:

: 96622-49-0
4,6-Benzyliden-N-benzoyl-methyl-β-D-allosaminid

: 6038-60-4,10396-56-2,10396-58-4,13013-43-9,25605-61-2,52885-44-6,52941-73-8,76792-23-9,76899-76-8,84048-42-0,99745-44-5,102735-68-2,116561-28-5,128657-58-9
(4aR,6R,7R,8S,8aS)-7-Amino-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

Guidance literature:: With potassium hydroxide; In ethanol; for 24h; Heating;

Reference yield:

: 6038-60-4,10396-56-2,10396-58-4,13013-43-9,25605-61-2,52885-44-6,52941-73-8,76792-23-9,76899-76-8,84048-42-0,99745-44-5,102735-68-2,116561-28-5,128657-58-9
(2R,4aS,6S,7S,8R,8aS)-7-Amino-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

Guidance literature:: Methyl2-benzoylamino-O⁴,O⁶-benzyliden-O³-toluol-4-sulfonyloxy-2-desoxy-α-D-glucopyranosid>, NaOH;
DOI:10.1016/S0008-6215(00)81199-4