[ScCl₂(1-(N(2,6-(i-Pr)2-C₆H₃))-2-(PPh₂N(2-(i-Pr)-C₆H₄))C₆H₄)]

Base Information

• Chemical Name: [ScCl₂(1-(N(2,6-(i-Pr)2-C₆H₃))-2-(PPh₂N(2-(i-Pr)-C₆H₄))C₆H₄)]
• CAS No.: 1020265-83-1
• Molecular Formula: C₃₉H₄₂Cl₂N₂PSc
• Molecular Weight: 685.612
• Mol file: 1020265-83-1.mol

Synonyms:[ScCl₂(1-(N(2,6-(i-Pr)2-C₆H₃))-2-(PPh₂N(2-(i-Pr)-C₆H₄))C₆H₄)]

Chemical Property of [ScCl₂(1-(N(2,6-(i-Pr)2-C₆H₃))-2-(PPh₂N(2-(i-Pr)-C₆H₄))C₆H₄)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [ScCl₂(1-(N(2,6-(i-Pr)2-C₆H₃))-2-(PPh₂N(2-(i-Pr)-C₆H₄))C₆H₄)]

There total 1 articles about [ScCl₂(1-(N(2,6-(i-Pr)2-C₆H₃))-2-(PPh₂N(2-(i-Pr)-C₆H₄))C₆H₄)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

[scandium(III)(chloride)3(tetrahydrofuran)3] (53317-83-2,14782-78-6) + [Li(1-(N(2,6-(i-Pr)2-C6H3))-2-(PPh2N(2-(i-Pr)-C6H4))C6H4)] → [ScCl2(1-(N(2,6-(i-Pr)2-C6H3))-2-(PPh2N(2-(i-Pr)-C6H4))C6H4)] (1020265-83-1)

Guidance literature:

In toluene; byproducts: LiCl; charging of bomb with (C6H3(i-Pr)2NC6H4PPh2NC6H4(i-Pr))Li and ScCl3(THF)3; condensing of toluene; stirring at 110°C overnight; cooling to room temp., filtration, removal of toluene in vac., sonication in hexanes; filtration; elem. anal.;

DOI:10.1016/j.jorganchem.2007.08.037

Reference yield: 86.0%

[ScCl2(1-(N(2,6-(i-Pr)2-C6H3))-2-(PPh2N(2-(i-Pr)-C6H4))C6H4)] (1020265-83-1) → [Sc(CH3)2(1-(N(2,6-(i-Pr)2-C6H3))-2-(PPh2N(2-(i-Pr)-C6H4)C6H4)] (1020265-88-6)

Guidance literature:

With n-C₄H₉Li; In toluene; byproducts: LiCl; charging of flask with (C6H3(i-Pr)2NC6H4PPh2NC6H4(i-Pr))ScCl2; condensing of toluene; cooling to 0°C; addn. of n-BuLi via syringe; warming to room temp.; stirring for 1 h; filtration; removal of toluene; elem. anal.;

DOI:10.1016/j.jorganchem.2007.08.037

Reference yield:

[ScCl2(1-(N(2,6-(i-Pr)2-C6H3))-2-(PPh2N(2-(i-Pr)-C6H4))C6H4)] (1020265-83-1) + methyllithium (917-54-4) → [Sc(CH3)2(1-(N(2,6-(i-Pr)2-C6H3))-2-(PPh2N(2-(i-Pr)-C6H4)C6H4)] (1020265-88-6)

Guidance literature:

In diethyl ether; byproducts: LiCl; treatment of (C6H3(i-Pr)2NC6H4PPh2NC6H4(i-Pr))ScCl2 with etheral soln. of methyl lithium (2 equiv.) at 0°C; filtration;

DOI:10.1016/j.jorganchem.2007.08.037

upstream raw materials:

[scandium(III)(chloride)3(tetrahydrofuran)3]

Downstream raw materials:

[Sc(CH₃)2(1-(N(2,6-(i-Pr)2-C₆H₃))-2-(PPh₂N(2-(i-Pr)-C₆H₄)C₆H₄)]