(E)-6-(4-((3'-cyano-4'-(dodecyloxy)biphenyl-4-yl)diazenyl)phenoxy)hexyl methacrylate

Base Information

• Chemical Name: (E)-6-(4-((3'-cyano-4'-(dodecyloxy)biphenyl-4-yl)diazenyl)phenoxy)hexyl methacrylate
• CAS No.: 1373207-60-3
• Molecular Formula: C₄₁H₅₃N₃O₄
• Molecular Weight: 651.89
• Mol file: 1373207-60-3.mol

Synonyms:(E)-6-(4-((3'-cyano-4'-(dodecyloxy)biphenyl-4-yl)diazenyl)phenoxy)hexyl methacrylate

Chemical Property of (E)-6-(4-((3'-cyano-4'-(dodecyloxy)biphenyl-4-yl)diazenyl)phenoxy)hexyl methacrylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-6-(4-((3'-cyano-4'-(dodecyloxy)biphenyl-4-yl)diazenyl)phenoxy)hexyl methacrylate

There total 9 articles about (E)-6-(4-((3'-cyano-4'-(dodecyloxy)biphenyl-4-yl)diazenyl)phenoxy)hexyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

(E)-4'-((4-(6-bromohexyloxy)phenyl)diazenyl)-4-(dodecyloxy)biphenyl-3-carbonitrile (1373207-56-7) + Methacryloyl chloride (920-46-7,26937-45-1) → (E)-6-(4-((3'-cyano-4'-(dodecyloxy)biphenyl-4-yl)diazenyl)phenoxy)hexyl methacrylate (1373207-60-3)

Guidance literature:

With potassium hydrogencarbonate; hydroquinone; In N,N-dimethyl-formamide; at 80 ℃; for 24h;

DOI:10.1016/j.polymer.2012.03.024

Reference yield:

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + C38H49BrN2O2 → (E)-6-(4-((3'-cyano-4'-(dodecyloxy)biphenyl-4-yl)diazenyl)phenoxy)hexyl methacrylate (1373207-60-3)

Guidance literature:

With potassium hydrogencarbonate; hydroquinone; In N,N-dimethyl-formamide; at 80 ℃; for 24h;

DOI:10.1002/cphc.201200585

Reference yield:

5-bromo-2-hydroxybenzonitrile (40530-18-5) → (E)-6-(4-((3'-cyano-4'-(dodecyloxy)biphenyl-4-yl)diazenyl)phenoxy)hexyl methacrylate (1373207-60-3)

Guidance literature:

Multi-step reaction with 4 steps

1.1: potassium carbonate; potassium iodide / acetone / 48 h / Reflux

2.1: n-butyllithium; Triisopropyl borate / tetrahydrofuran; hexane / 1.5 h / -78 - -70 °C

2.2: 20 °C

2.3: 1.5 h

3.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / tetrahydrofuran / 65 °C

4.1: potassium hydrogencarbonate; hydroquinone / N,N-dimethyl-formamide / 24 h / 80 °C

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; Triisopropyl borate; sodium carbonate; potassium carbonate; potassium hydrogencarbonate; hydroquinone; potassium iodide; In tetrahydrofuran; hexane; N,N-dimethyl-formamide; acetone;

DOI:10.1016/j.polymer.2012.03.024

upstream raw materials:

(E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4-bromophenyl)diazene

3-cyano-4-(dodecyloxy)phenylboronic acid

(E)-4'-((4-(6-bromohexyloxy)phenyl)diazenyl)-4-(dodecyloxy)biphenyl-3-carbonitrile

Methacryloyl chloride

Downstream raw materials:

C₄₁H₅₃N₃O₄