[(2E,6E)-(S)-8-((1R,2S,3S,4R)-3-Benzenesulfonylmethyl-2-benzyloxymethyl-3,4-dimethyl-cyclohexyl)-8-benzyloxymethoxy-2,6-dimethyl-octa-2,6-dienyloxy]-tert-butyl-dimethyl-silane

Base Information

Chemical Name:[(2E,6E)-(S)-8-((1R,2S,3S,4R)-3-Benzenesulfonylmethyl-2-benzyloxymethyl-3,4-dimethyl-cyclohexyl)-8-benzyloxymethoxy-2,6-dimethyl-octa-2,6-dienyloxy]-tert-butyl-dimethyl-silane
CAS No.:182625-06-5
Molecular Formula:C₄₇H₆₈O₆SSi
Molecular Weight:789.205
Hs Code.:

[(2E,6E)-(S)-8-((1R,2S,3S,4R)-3-Benzenesulfonylmethyl-2-benzyloxymethyl-3,4-dimethyl-cyclohexyl)-8-benzyloxymethoxy-2,6-dimethyl-octa-2,6-dienyloxy]-tert-butyl-dimethyl-silane

Synonyms:[(2E,6E)-(S)-8-((1R,2S,3S,4R)-3-Benzenesulfonylmethyl-2-benzyloxymethyl-3,4-dimethyl-cyclohexyl)-8-benzyloxymethoxy-2,6-dimethyl-octa-2,6-dienyloxy]-tert-butyl-dimethyl-silane

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Chemical Property of [(2E,6E)-(S)-8-((1R,2S,3S,4R)-3-Benzenesulfonylmethyl-2-benzyloxymethyl-3,4-dimethyl-cyclohexyl)-8-benzyloxymethoxy-2,6-dimethyl-octa-2,6-dienyloxy]-tert-butyl-dimethyl-silane

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Technology Process of [(2E,6E)-(S)-8-((1R,2S,3S,4R)-3-Benzenesulfonylmethyl-2-benzyloxymethyl-3,4-dimethyl-cyclohexyl)-8-benzyloxymethoxy-2,6-dimethyl-octa-2,6-dienyloxy]-tert-butyl-dimethyl-silane

There total 28 articles about [(2E,6E)-(S)-8-((1R,2S,3S,4R)-3-Benzenesulfonylmethyl-2-benzyloxymethyl-3,4-dimethyl-cyclohexyl)-8-benzyloxymethoxy-2,6-dimethyl-octa-2,6-dienyloxy]-tert-butyl-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 3587-60-8
Benzyloxymethyl chloride

: 182624-96-0
(2E,6E)-(S)-1-((1R,2S,3S,4R)-3-Benzenesulfonylmethyl-2-benzyloxymethyl-3,4-dimethyl-cyclohexyl)-8-(tert-butyl-dimethyl-silanyloxy)-3,7-dimethyl-octa-2,6-dien-1-ol

: 182625-06-5
[(2E,6E)-(S)-8-((1R,2S,3S,4R)-3-Benzenesulfonylmethyl-2-benzyloxymethyl-3,4-dimethyl-cyclohexyl)-8-benzyloxymethoxy-2,6-dimethyl-octa-2,6-dienyloxy]-tert-butyl-dimethyl-silane

Guidance literature:: With N-ethyl-N,N-diisopropylamine; at 50 ℃;
DOI:10.1016/0040-4039(96)01585-7

Reference yield:

: 121389-70-6
(E)-2-methyl-hept-2-en-6-yn-1-ol

: 182625-06-5
[(2E,6E)-(S)-8-((1R,2S,3S,4R)-3-Benzenesulfonylmethyl-2-benzyloxymethyl-3,4-dimethyl-cyclohexyl)-8-benzyloxymethoxy-2,6-dimethyl-octa-2,6-dienyloxy]-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) Cp₂ZrCl₂; 2.) I₂ / 1.) CH₂Cl₂, 0 deg C to rt; 2.) THF, -30 deg C

2: 83 percent / imidazole / dimethylformamide / Ambient temperature

3: 72 percent / t-BuLi / tetrahydrofuran

4: 94 percent / i-Pr₂NEt / 50 °C

With 1H-imidazole; zirconocene dichloride; iodine; tert.-butyl lithium; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1016/0040-4039(96)01585-7

Reference yield:

: (2E,6E)-7-iodo-2,6-dimethylhepta-2,6-dien-1-ol

: 182625-06-5
[(2E,6E)-(S)-8-((1R,2S,3S,4R)-3-Benzenesulfonylmethyl-2-benzyloxymethyl-3,4-dimethyl-cyclohexyl)-8-benzyloxymethoxy-2,6-dimethyl-octa-2,6-dienyloxy]-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1: 83 percent / imidazole / dimethylformamide / Ambient temperature

2: 72 percent / t-BuLi / tetrahydrofuran

3: 94 percent / i-Pr₂NEt / 50 °C

With 1H-imidazole; tert.-butyl lithium; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1016/0040-4039(96)01585-7