C₂₁H₃₄O₄SSi

Base Information

• Chemical Name: C₂₁H₃₄O₄SSi
• CAS No.: 1377314-15-2
• Molecular Formula: C₂₁H₃₄O₄SSi
• Molecular Weight: 410.65
• Mol file: 1377314-15-2.mol

Synonyms:C₂₁H₃₄O₄SSi

Chemical Property of C₂₁H₃₄O₄SSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₁H₃₄O₄SSi

There total 6 articles about C₂₁H₃₄O₄SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

C21H32O4SSi (1377313-92-2) → C21H34O4SSi (1377314-15-2)

Guidance literature:

With palladium on activated charcoal; hydrogen; In ethanol; for 24h; under 760.051 Torr; Inert atmosphere;

DOI:10.1021/ol301144a

Reference yield:

C15H18O3S → C21H34O4SSi (1377314-15-2)

Guidance literature:

Multi-step reaction with 5 steps

1.1: triethylamine / dichloromethane / 1 h / 0 - 20 °C / Inert atmosphere

2.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 12 h / 20 °C / Inert atmosphere

2.2: 5 h / 0 °C / Inert atmosphere

3.1: Dess-Martin periodane / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere

4.1: barium(II) hydroxide / tetrahydrofuran; water / 2 h / Inert atmosphere

5.1: palladium on activated charcoal; hydrogen / ethanol / 24 h / 760.05 Torr / Inert atmosphere

With palladium on activated charcoal; hydrogen; Dess-Martin periodane; triethylamine; 9-bora-bicyclo[3.3.1]nonane; barium(II) hydroxide; In tetrahydrofuran; ethanol; dichloromethane; water;

DOI:10.1021/ol301144a

Reference yield:

C21H32O3SSi (1377313-83-1) → C21H34O4SSi (1377314-15-2)

Guidance literature:

Multi-step reaction with 4 steps

1.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 12 h / 20 °C / Inert atmosphere

1.2: 5 h / 0 °C / Inert atmosphere

2.1: Dess-Martin periodane / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere

3.1: barium(II) hydroxide / tetrahydrofuran; water / 2 h / Inert atmosphere

4.1: palladium on activated charcoal; hydrogen / ethanol / 24 h / 760.05 Torr / Inert atmosphere

With palladium on activated charcoal; hydrogen; Dess-Martin periodane; 9-bora-bicyclo[3.3.1]nonane; barium(II) hydroxide; In tetrahydrofuran; ethanol; dichloromethane; water;

DOI:10.1021/ol301144a

upstream raw materials:

C₁₂H₁₂O₃S

C₂₁H₃₂O₃SSi

C₂₁H₃₄O₄SSi

C₂₁H₃₂O₄SSi