N-phenyl-N-(4-(10-(thiophen-2-yl)anthracen-9-yl)phenyl)benzenamine

Base Information

• Chemical Name: N-phenyl-N-(4-(10-(thiophen-2-yl)anthracen-9-yl)phenyl)benzenamine
• CAS No.: 1558010-10-8
• Molecular Formula: C₃₆H₂₅NS
• Molecular Weight: 503.667
• Mol file: 1558010-10-8.mol

Synonyms:N-phenyl-N-(4-(10-(thiophen-2-yl)anthracen-9-yl)phenyl)benzenamine

Chemical Property of N-phenyl-N-(4-(10-(thiophen-2-yl)anthracen-9-yl)phenyl)benzenamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-phenyl-N-(4-(10-(thiophen-2-yl)anthracen-9-yl)phenyl)benzenamine

There total 2 articles about N-phenyl-N-(4-(10-(thiophen-2-yl)anthracen-9-yl)phenyl)benzenamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

4-(diphenylamino)phenyl boronic acid (201802-67-7) + 2-(10-bromophenylanthracen-9-yl)thiophene → N-phenyl-N-(4-(10-(thiophen-2-yl)anthracen-9-yl)phenyl)benzenamine (1558010-10-8)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In water; toluene; for 24h; Inert atmosphere; Reflux;

DOI:10.1016/j.tet.2013.12.079

Reference yield:

9,10-Dibromoanthracene (523-27-3) → N-phenyl-N-(4-(10-(thiophen-2-yl)anthracen-9-yl)phenyl)benzenamine (1558010-10-8)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene / 15 h / Reflux; Inert atmosphere

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / toluene; water / 24 h / Inert atmosphere; Reflux

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In water; toluene; 1: |Stille Cross Coupling / 2: |Suzuki Coupling;

DOI:10.1016/j.tet.2013.12.079

Reference yield: 83.0%

N-phenyl-N-(4-(10-(thiophen-2-yl)anthracen-9-yl)phenyl)benzenamine (1558010-10-8) + ethenetetracarbonitrile (670-54-2) → N-(4-(1,2,2-tricyanoethene-1-yl)phenyl)-N-phenyl-4-(10-(thiophen-2-yl)anthracen-9-yl)benzenamine (1558010-11-9)

Guidance literature:

In N,N-dimethyl-formamide; at 140 ℃; for 36h; Inert atmosphere; Reflux;

DOI:10.1016/j.tet.2013.12.079

upstream raw materials:

9,10-Dibromoanthracene

4-(diphenylamino)phenyl boronic acid

Downstream raw materials:

N-(4-(1,2,2-tricyanoethene-1-yl)phenyl)-N-phenyl-4-(10-(thiophen-2-yl)anthracen-9-yl)benzenamine

1-(5-(10-(4-(diphenylamino)phenyl)anthracen-9-yl)thiophen-2-yl)ethene-1,2,2-tricarbonitrile