(η(5)-pentamethylcyclopentadienyl)iodo(perfluorobenzyl)carbonylcobalt(III)

Base Information

• Chemical Name: (η(5)-pentamethylcyclopentadienyl)iodo(perfluorobenzyl)carbonylcobalt(III)
• CAS No.: 184682-63-1
• Molecular Formula: C₁₈H₁₅CoF₇IO
• Molecular Weight: 566.203
• Mol file: 184682-63-1.mol

Synonyms:(η(5)-pentamethylcyclopentadienyl)iodo(perfluorobenzyl)carbonylcobalt(III)

Chemical Property of (η(5)-pentamethylcyclopentadienyl)iodo(perfluorobenzyl)carbonylcobalt(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η(5)-pentamethylcyclopentadienyl)iodo(perfluorobenzyl)carbonylcobalt(III)

There total 1 articles about (η(5)-pentamethylcyclopentadienyl)iodo(perfluorobenzyl)carbonylcobalt(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

[(pentamethylcyclopentadienyl)Co(CO)2] (12129-77-0) + 1-(difluoroiodomethyl)-2,3,4,5,6-pentafluorobenzene (79865-03-5) → (η(5)-pentamethylcyclopentadienyl)iodo(perfluorobenzyl)carbonylcobalt(III) (184682-63-1)

Guidance literature:

In benzene; N2-atmosphere; stirring (room temp., 1 h); elem. anal.;

DOI:10.1021/om9607255

Reference yield: 98.0%

(η(5)-pentamethylcyclopentadienyl)iodo(perfluorobenzyl)carbonylcobalt(III) (184682-63-1) + Dimethyl(phenyl)phosphine (672-66-2) → Co(P(CH3)2C6H5)I((CH3)4C5CH2C6F4CF2) (184682-69-7)

Guidance literature:

In tetrahydrofuran; N2-atmosphere; stirring (room temp., 19 h); evapn. (vac.);

DOI:10.1021/om9607255

Reference yield: 83.0%

(η(5)-pentamethylcyclopentadienyl)iodo(perfluorobenzyl)carbonylcobalt(III) (184682-63-1) + trimethylphosphane (594-09-2) → (η(5)-pentamethylcyclopentadienyl)iodo(perfluorobenzyl)(trimethylphosphine)cobalt(III) (184682-65-3)

Guidance literature:

In benzene; N2-atmosphere; stirring (room temp., 6 h); evapn. (vac.), CH2Cl2 addn., filtering, crystn. on concg. and hexanes addn. (-60°C); elem. anal.;

DOI:10.1021/om9607255

upstream raw materials:

[(pentamethylcyclopentadienyl)Co(CO)2]

1-(difluoroiodomethyl)-2,3,4,5,6-pentafluorobenzene

Downstream raw materials:

Co(P(CH₃)3)I((CH₃)4C₅CH₂C₆F₄CF₂)

hydrogen fluoride

(η(5)-pentamethylcyclopentadienyl)iodo(perfluorobenzyl)(trimethylphosphine)cobalt(III)

Co(P(CH₃)2C₆H₅)I((CH₃)4C₅CH₂C₆F₄CF₂)