tert-butyldiphenylsilyl 4-(tert-butyldiphenylsilyloxy)-2-methylbutanoate

Base Information

Chemical Name:tert-butyldiphenylsilyl 4-(tert-butyldiphenylsilyloxy)-2-methylbutanoate
CAS No.:949163-11-5
Molecular Formula:C₃₇H₄₆O₃Si₂
Molecular Weight:594.941
Hs Code.:

Synonyms:tert-butyldiphenylsilyl 4-(tert-butyldiphenylsilyloxy)-2-methylbutanoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tert-butyldiphenylsilyl 4-(tert-butyldiphenylsilyloxy)-2-methylbutanoate

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Technology Process of tert-butyldiphenylsilyl 4-(tert-butyldiphenylsilyloxy)-2-methylbutanoate

There total 1 articles about tert-butyldiphenylsilyl 4-(tert-butyldiphenylsilyloxy)-2-methylbutanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: 1679-47-6
3-methyltetrahydro-2-furanone

: 949163-11-5
tert-butyldiphenylsilyl 4-(tert-butyldiphenylsilyloxy)-2-methylbutanoate

Guidance literature:: 3-methyltetrahydro-2-furanone; With sodium hydroxide; In ethanol; water; for 3.5h; Heating;

tert-butylchlorodiphenylsilane; With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; for 15h; Further stages.;
DOI:10.1002/ejoc.200700086

Reference yield: 76.0%

: 949163-11-5
tert-butyldiphenylsilyl 4-(tert-butyldiphenylsilyloxy)-2-methylbutanoate

: 204316-52-9
4-(tert-butyldiphenylsilyloxy)-2-methylbutan-1-ol

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; toluene; for 2.5h;
DOI:10.1002/ejoc.200700086

Reference yield:

: 949163-11-5
tert-butyldiphenylsilyl 4-(tert-butyldiphenylsilyloxy)-2-methylbutanoate

: C₃₂H₄₂O₆Si

Guidance literature:: Multi-step reaction with 7 steps

1.1: 76 percent / DIBAL-H / CH₂Cl₂; toluene / 2.5 h

2.1: dimethyl sulfoxide; triethylamine; SO₃*pyridine / CH₂Cl₂ / 0.5 h

3.1: CH₂Cl₂

4.1: CH₂Cl₂ / 0.33 h / 20 °C

5.1: NH₄Cl; aq. HCl / CH₂Cl₂ / 0.5 h

6.1: 360 mg / air / ethyl acetate / 72 h / 25 °C

7.1: BuLi / tetrahydrofuran; hexane / 0.25 h / -78 °C

7.2: tetrahydrofuran; hexane / 3 h / -78 °C

With hydrogenchloride; n-butyllithium; air; pyridine-SO₃ complex; diisobutylaluminium hydride; ammonium chloride; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; hexane; dichloromethane; ethyl acetate; toluene;
DOI:10.1002/ejoc.200700086