C₃₂H₄₅NO₄Si

Base Information

Chemical Name:C₃₂H₄₅NO₄Si
CAS No.:1395688-49-9
Molecular Formula:C₃₂H₄₅NO₄Si
Molecular Weight:535.799
Hs Code.:

C<sub>32</sub>H<sub>45</sub>NO<sub>4</sub>Si

Synonyms:C₃₂H₄₅NO₄Si

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Chemical Property of C₃₂H₄₅NO₄Si

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Technology Process of C₃₂H₄₅NO₄Si

There total 15 articles about C₃₂H₄₅NO₄Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 1395688-41-1
C₂₆H₃₁NO₄

: 69739-34-0
t-butyldimethylsiyl triflate

: 1395688-49-9
C₃₂H₄₅NO₄Si

Guidance literature:: With triethylamine; In dichloromethane; at 20 ℃; for 3h;
DOI:10.1021/jo302362b

Reference yield:

: 1395687-54-3
(R)-1-allyl-5-(benzyloxy)piperidin-2-one

: 1395688-49-9
C₃₂H₄₅NO₄Si

Guidance literature:: Multi-step reaction with 13 steps

1.1: trifluoromethylsulfonic anhydride; 2,6-di-tert-butyl-4-methylpyridine / dichloromethane

2.1: lithium naphthalenide / tetrahydrofuran / 1 h / -40 °C

3.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 1 h / -78 °C

4.1: hydrogenchloride / tetrahydrofuran; water / 1.5 h / 20 - 50 °C

4.3: CSA / 0.17 h / 90 °C

5.1: sodium hydride; tetra-(n-butyl)ammonium iodide / N,N-dimethyl-formamide / 18 h / 20 °C

6.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / dichloromethane / 1 h / 20 °C

7.1: triethylamine / dichloromethane / 0.5 h / 0 °C

8.1: titanium(IV) isopropylate; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / toluene / 12 h / 85 °C

9.1: hydrogenchloride / acetone / 3 h / Reflux

10.1: potassium hexamethylsilazane / tetrahydrofuran / -50 °C

10.2: 0 °C

11.1: palladium 10% on activated carbon; hydrogen / ethyl acetate / 3 h / 20 °C / 760.05 Torr

12.1: samarium diiodide; N,N,N,N,N,N-hexamethylphosphoric triamide / methanol / 12 h / -78 °C

13.1: triethylamine / dichloromethane / 3 h / 20 °C

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; titanium(IV) isopropylate; hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; 2,6-di-tert-butyl-4-methylpyridine; samarium diiodide; oxalyl dichloride; trifluoromethylsulfonic anhydride; palladium 10% on activated carbon; hydrogen; tetra-(n-butyl)ammonium iodide; potassium hexamethylsilazane; sodium hydride; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; methanol; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide; acetone; toluene; 3.1: |Swern Oxidation / 3.2: |Swern Oxidation;
DOI:10.1021/jo302362b

Reference yield:

: 1395687-70-3
(3R,6R)-6-[2-(1,3-dioxolan-2-yl)ethyl]-1-allyl-6-vinylpiperidin-3-ol

: 1395688-49-9
C₃₂H₄₅NO₄Si

Guidance literature:: Multi-step reaction with 11 steps

1.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 1 h / -78 °C

2.1: hydrogenchloride / tetrahydrofuran; water / 1.5 h / 20 - 50 °C

2.3: CSA / 0.17 h / 90 °C

3.1: sodium hydride; tetra-(n-butyl)ammonium iodide / N,N-dimethyl-formamide / 18 h / 20 °C

4.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / dichloromethane / 1 h / 20 °C

5.1: triethylamine / dichloromethane / 0.5 h / 0 °C

6.1: titanium(IV) isopropylate; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / toluene / 12 h / 85 °C

7.1: hydrogenchloride / acetone / 3 h / Reflux

8.1: potassium hexamethylsilazane / tetrahydrofuran / -50 °C

8.2: 0 °C

9.1: palladium 10% on activated carbon; hydrogen / ethyl acetate / 3 h / 20 °C / 760.05 Torr

10.1: samarium diiodide; N,N,N,N,N,N-hexamethylphosphoric triamide / methanol / 12 h / -78 °C

11.1: triethylamine / dichloromethane / 3 h / 20 °C

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; titanium(IV) isopropylate; hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; samarium diiodide; oxalyl dichloride; palladium 10% on activated carbon; hydrogen; tetra-(n-butyl)ammonium iodide; potassium hexamethylsilazane; sodium hydride; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; methanol; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide; acetone; toluene; 1.1: |Swern Oxidation / 1.2: |Swern Oxidation;
DOI:10.1021/jo302362b