Basidalin

Base Information

Chemical Name:Basidalin
CAS No.:82501-56-2
Molecular Formula:C₆H₅NO₃
Molecular Weight:139.111
Hs Code.:
Nikkaji Number:J3.538.584C
Wikidata:Q76386717
Metabolomics Workbench ID:98316
ChEMBL ID:CHEMBL5201826
Mol file:82501-56-2.mol

Synonyms:4-amino-5-(formylmethylene)-2(5H)-furanone;basidalin

Suppliers and Price of Basidalin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Basidalin

Chemical Property:

Vapor Pressure:0.068mmHg at 25°C
Boiling Point:229.8°C at 760 mmHg
Flash Point:120°C
PSA：69.39000
Density:1.551g/cm³
LogP:0.16890
XLogP3:-1
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:1
Exact Mass:139.026943022
Heavy Atom Count:10
Complexity:239

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=C(C(=CC=O)OC1=O)N
Isomeric SMILES:C1=C(/C(=C\C=O)/OC1=O)N

Technology Process of Basidalin

There total 10 articles about Basidalin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: (Z)-5-((1,3-dithian-2-yl)methylene)-4-aminofuran-2(5H)-one

: 82501-56-2
(Z)-basidalin

Guidance literature:: With calcium carbonate; methyl iodide; In water; acetone; at 60 ℃; for 5h;
DOI:10.1021/acs.joc.6b01255

Reference yield: 65.0%

: 158142-91-7
(E)-4-amino-5-(2-hydroxy-3,3-dimethyl-4-pentenylidene)-2(5H)-furanone

: 82501-56-2
(E)-basidalin

Guidance literature:: With lead(IV) acetate; In dichloromethane; -78 deg C, 2 h; r.t., 1.5 h;
DOI:10.1016/S0040-4020(01)85262-5

Reference yield:

: 158142-90-6
(E)-4-amino-5-(3,3-dimethyl-2-oxo-4-pentenylidene)-2(5H)-furanone

: 82501-56-2
(E)-basidalin

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / CeCl₃*7H₂O, NaBH₄ / methanol; CH₂Cl₂ / 1 h / -70 - -30 °C

2: 65 percent / Pb(OAc)4 / CH₂Cl₂ / -78 deg C, 2 h; r.t., 1.5 h

With lead(IV) acetate; sodium tetrahydroborate; cerium(III) chloride; In methanol; dichloromethane;
DOI:10.1016/S0040-4020(01)85262-5